[Ru(5,5'-divinyl-2,2'-bipyridine)(η⁶-benzene)(Cl)](Cl) | 1604834-88-9

• 英文名称: [Ru(5,5'-divinyl-2,2'-bipyridine)(η⁶-benzene)(Cl)](Cl)
• CAS: 1604834-88-9
• 化学式: C₂₀H₁₈ClN₂Ru*Cl
• 分子量: 458.352
• InChiKey: JHZNTXHOHDREEG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(5,5'-divinyl-2,2'-bipyridine)(η⁶-benzene)(Cl)](Cl) 、 2,6-二(1-甲基苯并咪唑-2-基)吡啶 以 乙醇 为溶剂， 反应 0.33h， 生成 [Ru(2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl)pyridine)(5,5'-divinyl-2,2'-bipyridine)(Cl)](Cl)
  参考文献：
  名称：

  Water Oxidation by an Electropolymerized Catalyst on Derivatized Mesoporous Metal Oxide Electrodes

  摘要：

  A general electropolymerization/electro-oligomerization strategy is described for preparing spatially controlled, multicomponent films and surface assemblies having both light harvesting chromophores and water oxidation catalysts on metal oxide electrodes for applications in dye-sensitized photoelectrosynthesis cells (DSPECs). The chromophore/catalyst ratio is controlled by the number of reductive electrochemical cycles. Catalytic rate constants for water oxidation by the polymer films are similar to those for the phosphonated molecular catalyst on metal oxide electrodes, indicating that the physical properties of the catalysts are not significantly altered in the polymer films. Controlled potential electrolysis shows sustained water oxidation over multiple hours with no decrease in the catalytic current.

  DOI：

  10.1021/ja502464s
• 作为产物：
  描述：

  [RuCl2(benzene)]2 、 5,5-二乙烯基-2,2-联吡啶 以 甲醇 为溶剂， 生成 [Ru(5,5'-divinyl-2,2'-bipyridine)(η⁶-benzene)(Cl)](Cl)
  参考文献：
  名称：

  Water Oxidation by an Electropolymerized Catalyst on Derivatized Mesoporous Metal Oxide Electrodes

  摘要：

  A general electropolymerization/electro-oligomerization strategy is described for preparing spatially controlled, multicomponent films and surface assemblies having both light harvesting chromophores and water oxidation catalysts on metal oxide electrodes for applications in dye-sensitized photoelectrosynthesis cells (DSPECs). The chromophore/catalyst ratio is controlled by the number of reductive electrochemical cycles. Catalytic rate constants for water oxidation by the polymer films are similar to those for the phosphonated molecular catalyst on metal oxide electrodes, indicating that the physical properties of the catalysts are not significantly altered in the polymer films. Controlled potential electrolysis shows sustained water oxidation over multiple hours with no decrease in the catalytic current.

  DOI：

  10.1021/ja502464s