Fe(1,5-C8H12)(η-C5H5) | 70713-60-9

• 英文名称: Fe(1,5-C8H12)(η-C5H5)
• CAS: 70713-60-9
• 化学式: C₁₃H₁₇Fe
• 分子量: 229.125
• InChiKey: PVDSVPYWQODDTF-GCOBPYNFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  、 Fe(1,5-C8H12)(η-C5H5) 以 light petroleum 为溶剂， 生成
  参考文献：
  名称：

  Formation of η⁶-arene-closo-carbaferraboranes by the reaction of a closo-carbaborane with cyclo-octadiene (η-cyclopentadienyl)iron in the presence of arenes: molecular structure of [closo-1-(η⁶-PhMe)-2,4-Me₂-1,2,4-FeC₂B₉H₉]

  摘要：

  2,3-Me2-2,3-C2B9H9与[Fe(1,5-C8H12)(δ--C5H5)]在苯、甲苯、邻二甲苯中反应，或与过量的萘在轻质石油中反应，得到[closeno-1-(δ-6-arene)-2,4-Me2-1,2,4-FeC2B9H9]络合物，甲苯络合物的特征通过 X 射线晶体学得以确定；δ-6-萘络合物与配体 L = CO 或 P(OMe)3 反应生成[closeno-1,1,1-L3-2,4-Me2-1,2,4-FeC2B9H9]。

  DOI：

  10.1039/c39810000871

文献信息

• Metallaborane chemistry. Part 12. Electron hyper-deficient carbametallaboranes containing iron–iron, iron–cobalt, and iron–platinum connectivities: molecular and crystal structure of [CoFe(Me₄C₄B₈H₈)(PEt₃)₂]
  作者：Geoffrey K. Barker、Maria P. Garcia、Michael Green、F. Gordon A. Stone、Alan J. Welch

  DOI：10.1039/dt9820001679

  日期：——

  bipyramids fused about a common iron apical vertex and sharing a double-capping BH function. Crystals are orthorhombic, space group P212121 with a= 16.533(5), b= 11.012(2), c= 16.279(3)Å, and four molecules per unit cell. Using 3 496 amplitudes recorded on a four-circle diffractometer at 291 ± 1 K the structure has been refined to R 0.043. The Co–Fe distance is 2.5300(8)Å; 0.05 Å longer than that in

  二氢氨基甲酸呋喃硼烷[FeH 2（2,3-Me 2 -2,3-C 2 B 4 H 4）2 ]与[Co（PEt 3）4 ]，[Pt 2（μ-cod）（PEt 3）4 ]（COD =环辛-1,5-二烯），和的[Fe（COD）（η-C 5 H ^ 5）]，得到分别的二元金属物种[由CoFe（ME 4 ç 4乙8 ħ 8） （PEt 3）2 ]，[FePt（Me 4 C 4 B 8 H 8）（PEt3） 2 ]和[铁2（ME 4 ç 4乙8 ħ 8）（η-C 5 H ^ 5）]，其中的每一个设有一个金属-金属的连接。对铁-钴分子的X射线衍射研究表明，它属于结构家族，涉及两个五角形双锥体，它们围绕一个共同的铁顶顶点融合，并具有双帽BH功能。晶体是正交晶体，空间群P 2 1 2 1 2 1具有a = 16.533（5）， b = 11.012（2）， c= 16.279（3）Å，每个晶胞有四个分子。使用在291±1
• Ein- und Mehrkernkomplexe des 9,10-Dihydro-9,10-dimethyl-9,10-diboraanthracens
  作者：Peter Mu¨ller、Hans Pritzkow、Walter Siebert

  DOI：10.1016/s0022-328x(96)06217-1

  日期：1996.11

  A series of new transitionmetal complexes of 9,10-dihydro-9,10-dimethyl-9,10-diboraanthracene (1) was synthesized and characterized, Mono-, di-, and trinuclear species were isolated, indicating the diversity of the ligand properties of 1. The reaction of 1 with an excess of [CoCp(C2H4)(2)] yields the known 18 VE sandwich complex [(CoCp)1] (2) and the new paramagnetic 32 VE triple-decker complex [(CoCp)(2)1] (3), [RhCp(C2H4)(2)] forms with 1 the 18 VE sandwich complex [(RhCp)1] (4). Two equivalents of [FeCp(C8H12)] and 1 yield the diamagnetic 30 VE triple-decker [(FeCp)(2)1] (5) with the iron atoms eta(6) bifacially coordinated to the heterocycle. The dianion 1(2-) reacts with [CoCp* Br](2) to form [(CoCp*)(3)1] (6) with three independent 18 VE metal centres. The reactions of 1(2-) with [Ni(C3H5)Br](2) and [Ni(C4H7)Br](2) lead to the 30 VE triple-decker complexes [Ni(C3H5)}(2)1] (7a) and [Ni(C4H7)}(2)1] (7b) respectively. [Pd(C8H12)(2)] and [Pt(C8H12)(2)] yield in the reaction with 1 the 18 VE complexes [Pd(C8H12)1] (8) and [Pt(C8H12)1] (9) respectively. The complex [Ni(C6H5)(2)PCH2}(2)1] (10) is generated by reacting 1(2-) with [Ni(C6H5)(2)PCH2}Cl-2(2)]. Two equivalents of the radical anion 1(-) and Ni2+ form the labile 18 VE sandwich [Ni(1)(2)] (11). The constitutions of the new complexes have been derived from spectroscopic data and elemental analyses, and were confirmed by X-ray structure analyses for 5, 6, 7a, 8, 9, and 10.