1,4-bis(trichlorostannyl)butane diaquo adduct | 272127-83-0

• 英文名称: 1,4-bis(trichlorostannyl)butane diaquo adduct
• CAS: 272127-83-0
• 化学式: C₄H₁₂Cl₆O₂Sn₂
• 分子量: 542.276
• InChiKey: UDSQYABIWNOMIC-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,4-bis(trichlorostannyl)butane diaquo adduct 以 氘代氯仿 为溶剂， 生成 α,ω-bis-(trichlorostannyl)butane
  参考文献：
  名称：

  α,ω-Bis(trichlorostannyl)alkanes:  Unravelling the Hydrolysis Pathway to Organotin-oxo Oligomers

  摘要：

  New alpha,omega -bis(trichlorostannyl)alkanes, Cl3Sn(CH2)(n)SnCl3 [n = 3-5, 8], have been synthesized via tin-phenyl bond cleavage reactions on alpha,omega -bis(triphenylstannyl)alkanes, Ph3Sn(CH2)(n)SnPh3 [n = 3-5, 8], using either SnCl4 or concentrated hydrochloric acid. Some key missing links, (H2O)Cl3Sn(CH2)(3)SnCl3(H2O) (1a) and (H2O)(2)Cl3Sn(CH2)(3)SnCl3(H2O)(2) (6), in the hydrolysis pathway of organotin trichlorides were identified. Crystal structures of the nonassociated di-tin compounds (H2O)Cl3Sn(CH2)(3)SnCl3(H2O) (1a) and (H2O)(2)Cl3Sn(CH2)(3)SnCl3(H2O)(2) (6, isolated as the 18-crown-6 cocrystal acetonitrile solvate) as well as the polymeric hydrolysis product [H2O(OH)Cl2Sn(CH2)(3)SnCl2(OH)H2O . 2H(2)O](n) (7 . 2H(2)O) are reported.

  DOI：

  10.1021/om010202j
• 作为产物：
  描述：

  α,ω-bis-(trichlorostannyl)butane 、 水 以 氯仿 为溶剂， 生成 1,4-bis(trichlorostannyl)butane diaquo adduct
  参考文献：
  名称：

  α,ω-Bis(trichlorostannyl)alkanes:  Unravelling the Hydrolysis Pathway to Organotin-oxo Oligomers

  摘要：

  New alpha,omega -bis(trichlorostannyl)alkanes, Cl3Sn(CH2)(n)SnCl3 [n = 3-5, 8], have been synthesized via tin-phenyl bond cleavage reactions on alpha,omega -bis(triphenylstannyl)alkanes, Ph3Sn(CH2)(n)SnPh3 [n = 3-5, 8], using either SnCl4 or concentrated hydrochloric acid. Some key missing links, (H2O)Cl3Sn(CH2)(3)SnCl3(H2O) (1a) and (H2O)(2)Cl3Sn(CH2)(3)SnCl3(H2O)(2) (6), in the hydrolysis pathway of organotin trichlorides were identified. Crystal structures of the nonassociated di-tin compounds (H2O)Cl3Sn(CH2)(3)SnCl3(H2O) (1a) and (H2O)(2)Cl3Sn(CH2)(3)SnCl3(H2O)(2) (6, isolated as the 18-crown-6 cocrystal acetonitrile solvate) as well as the polymeric hydrolysis product [H2O(OH)Cl2Sn(CH2)(3)SnCl2(OH)H2O . 2H(2)O](n) (7 . 2H(2)O) are reported.

  DOI：

  10.1021/om010202j