[Rh(CO)(triphenylphosphine)2(water)]CF3SO3 | 132854-46-7

• 英文名称: [Rh(CO)(triphenylphosphine)2(water)]CF3SO3
• 英文别名: trans-{(Ph3P)2Rh(CO)(H2O)}(1+)(CF3SO3)(1-)；trans-[Rh(PPh3)2(CO)(H2O)]CF3SO3
• CAS: 132854-46-7
• 化学式: CF₃O₃S*C₃₇H₃₂O₂P₂Rh
• 分子量: 822.583
• InChiKey: SZWWEEARHQTUAB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Rh(CO)(triphenylphosphine)2(water)]CF3SO3 以 苯 为溶剂， 以99%的产率得到trans-Rh(PPh3)2(CO)(triflate)
  参考文献：
  名称：

  Evaluation of Triflate Displacement by Water in CH₂Cl₂ Solution:  Comparison of trans-[Rh(CO)(PPh₃)₂(OSO₂CF₃)] and the Crystalline Salt trans-[Rh(CO)(PPh₃)₂(OH₂)][OTf]

  摘要：

  DOI：

  10.1021/ic951287h
• 作为产物：
  描述：

  {(PPh3)2Rh(CO)(OC3(t-Bu)2)}(triflate) 在 H₂O 作用下， 生成 [Rh(CO)(triphenylphosphine)2(water)]CF3SO3
  参考文献：
  名称：

  Song, Linsheng; Arif, Atta M.; Stang, Peter J., Organometallics, 1990, vol. 9, # 10, p. 2792 - 2797

  摘要：

  DOI：

文献信息

• Formation and characterization of simple, stable, coordinated water complexes of rhodiumand iridium. The crystal structure of trans-[Rh(PPh3)2(CO)(H3O]+CF3SO3−
  作者：Peter J. Stang、Linsheng Song、Yo-Hsin Huang、Atta M. Arif

  DOI：10.1016/0022-328x(91)86299-6

  日期：1991.3

  Reaction of trans-(Ph3P)2Rh(CO)(OSO2CF3) and trans-(Ph3P)2Ir(CO)(OSO2CF3) with water in benzene results in the formation of stable trans-[(Ph3P)2Rh(CO)(H2O)] + CF3SO3- and trans-[(Ph3P)2Ir(CO)(H2O)] + CF3SO3-, respectively. The crystal structure of the Rh-complex is reported.
• Cationic rhodium(I) complexes formed in the reactions of HRh(CO)L3 (L=PPh3, P(OPh)3) complexes with silver(I) salts
  作者：Anna M Trzeciak、Zofia Olejnik、Józef J Ziółkowski、Tadeusz Lis

  DOI：10.1016/s0020-1693(02)01551-7

  日期：2003.7

  The reactions of HRh(CO)L-3 (L=PPh3, P(OPh)(3)) complexes with AgY (Y=BF4-, CF3SO3-, PF6-) lead to [Rh(CO)(PPh3)(2)(H2O)]Y and [Rh (CO)(P(OPh)(3))(3)]Y compounds. The solvolysis of [Rh(CO)(PPh3)(2)(H2O)]PF6 in ethanol produced a crystalline trans-[Rh(CO)(PPh3)(2)(OPOF2)] complex containing distorted square-planar rhodium center. The different arrangement of OPOF2- ligands found in two crystallographically independent molecules is connected with the presence of intra- and intermolecular C-H...O hydrogen bonds involving both oxygen atoms of each OPOF2- anion. The reaction of [Rh(CO)(P(OPh)(3))(3)]Y (Y=BF4-, PF6-) in solution with CO leads to [Rh(CO)(2)(P(OPh)(3))(3)]Y and with P(OPh)(3) to [Rh(P(OPh)(3))(4)]Y complexes. The [Rh(P(OPh)(3))(4)]PF6 complex was also obtained as a final reaction product of HRh(P(OPh)(3))(4) with AgPF6. (C) 2003 Elsevier Science B.V. All rights reserved.