[RuCl3(2,6-bis(2-naphthyridyl)pyridine)] | 850753-48-9

• 英文名称: [RuCl3(2,6-bis(2-naphthyridyl)pyridine)]
• CAS: 850753-48-9
• 化学式: C₂₁H₁₃Cl₃N₅Ru
• 分子量: 542.797
• InChiKey: ZPYGGAIPWSDEFC-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 2,6-di(1,8-naphthyridin-2-yl)pyridine 、 [RuCl3(2,6-bis(2-naphthyridyl)pyridine)] 在 (C₂H₅)3N 作用下， 以 further solvent(s) 为溶剂， 以69%的产率得到bis(2,6-bis(2-naphthyridyl)pyridine)ruthenium(II) hexafluorophosphate
  参考文献：
  名称：

  Synthesis, chemical- and electrochemical properties of ruthenium(II) complexes bearing 2,6-bis(2-naphthyridyl)pyridine

  摘要：

  Ruthenium complexes with a terpyridine-analogous ligand, 2,6-bis(2-naphthyridyl)pyridine (bnp), have been synthesized and their chemical and electrochemical properties investigated. The structures of [Ru(bnp)(tpy)](PF6)(2) (1) and [Ru(bnP)(2)](PF6)(2) (2) were determined by the X-ray structure analysis. The bnp localized redox potentials of I and 2 showed significant positive shift by 260290 mV relative to the analogous Ru-terpyridine complexes. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.12.008
• 作为产物：
  描述：

  水合三氯化钌 、 2,6-di(1,8-naphthyridin-2-yl)pyridine 以 乙醇 为溶剂， 以90%的产率得到[RuCl3(2,6-bis(2-naphthyridyl)pyridine)]
  参考文献：
  名称：

  Synthesis, chemical- and electrochemical properties of ruthenium(II) complexes bearing 2,6-bis(2-naphthyridyl)pyridine

  摘要：

  Ruthenium complexes with a terpyridine-analogous ligand, 2,6-bis(2-naphthyridyl)pyridine (bnp), have been synthesized and their chemical and electrochemical properties investigated. The structures of [Ru(bnp)(tpy)](PF6)(2) (1) and [Ru(bnP)(2)](PF6)(2) (2) were determined by the X-ray structure analysis. The bnp localized redox potentials of I and 2 showed significant positive shift by 260290 mV relative to the analogous Ru-terpyridine complexes. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.12.008