bis(6,6'-dibromo-2,2'-bipyridine-N,N')copper(I) hexafluorophosphate | 220180-60-9

• 英文名称: bis(6,6'-dibromo-2,2'-bipyridine-N,N')copper(I) hexafluorophosphate
• CAS: 220180-60-9
• 化学式: C₂₀H₁₂Br₄CuN₄*F₆P
• 分子量: 836.468
• InChiKey: SIXNZPKQXAUCNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(6,6'-dibromo-2,2'-bipyridine-N,N')copper(I) hexafluorophosphate 、 sodium perchlorate 以 水 、 乙腈 为溶剂， 生成 bis(6,6'-dibromo-2,2'-bipyridine-N,N')copper(I) perchlorate
  参考文献：
  名称：

  [CuL₂][ClO₄] and [AgL₂][BF₄], whereL= 6,6'-Dibromo-2,2'-bipyridine

  摘要：

  The complexes bis(6,6'-dibromo-2,2'-bipyridine-N,N')copper(I) perchlorate, [Cu(C10H6Br2N2)(2)]ClO4, and bis(6,6'-dibromo-2,2'-bipyridine-N,N')silver(I) tetrafluoroborate, [Ag(C10H6Br2N2)(2)]BF4, both contain four-coordinate pseudo-tetrahedral metal centres, in which the two bidentate chelating ligands are nearly mutually perpendicular; the average dihedral angle between the two MN2 planes is 87.9 degrees for M = Cu but only 75 degrees for M = Ag, which reflects the lesser inter-ligand steric interactions in the silver(I) complex, arising from the greater metal-ligand bond distances. For both complexes, the crystal packing is dominated by intermolecular Br ... Br interactions.

  DOI：

  10.1107/s0108270198009159
• 作为产物：
  描述：

  tetrakis(actonitrile)copper(I) hexafluorophosphate 、 6,6'-二溴-2,2'-联吡啶 以 甲醇 为溶剂， 生成 bis(6,6'-dibromo-2,2'-bipyridine-N,N')copper(I) hexafluorophosphate
  参考文献：
  名称：

  [CuL₂][ClO₄] and [AgL₂][BF₄], whereL= 6,6'-Dibromo-2,2'-bipyridine

  摘要：

  The complexes bis(6,6'-dibromo-2,2'-bipyridine-N,N')copper(I) perchlorate, [Cu(C10H6Br2N2)(2)]ClO4, and bis(6,6'-dibromo-2,2'-bipyridine-N,N')silver(I) tetrafluoroborate, [Ag(C10H6Br2N2)(2)]BF4, both contain four-coordinate pseudo-tetrahedral metal centres, in which the two bidentate chelating ligands are nearly mutually perpendicular; the average dihedral angle between the two MN2 planes is 87.9 degrees for M = Cu but only 75 degrees for M = Ag, which reflects the lesser inter-ligand steric interactions in the silver(I) complex, arising from the greater metal-ligand bond distances. For both complexes, the crystal packing is dominated by intermolecular Br ... Br interactions.

  DOI：

  10.1107/s0108270198009159