(tetracarbonyl)(tetraphenylimidodiselenophosphinato-κ2Se,Se')rhenium | 765936-40-1

• 英文名称: (tetracarbonyl)(tetraphenylimidodiselenophosphinato-κ2Se,Se')rhenium
• 英文别名: Re(CO)4[Ph2P(Se)NP(Se)Ph2-κ2Se,Se']；[Re(CO)4(Ph2P(Se)NP(Se)Ph2-κ2Se)]；[Re(CO)4(Ph2P(Se)NP(Se)Ph2-Se,Se')]
• CAS: 765936-40-1
• 化学式: C₂₈H₂₀NO₄P₂ReSe₂
• 分子量: 840.546
• InChiKey: ZHDNIJNYDFSOQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  五羰基溴铼(I) 、 (tetracarbonyl)(tetraphenylimidodiselenophosphinato-κ2Se,Se')rhenium 以 甲苯 为溶剂， 以80%的产率得到(μ-bromido)(hexacarbonyl)(μ-tetraphenylimidodiselenophosphinato-κ2Se,Se')dirhenium
  参考文献：
  名称：

  Formation of carbonylrhenium cryptates with alkali metal cations: Coordination chemistry studies of [Ph2P(E)NP(E)Ph2]−, E=O, S, Se towards ReBr(CO)5

  摘要：

  Reaction of ReBr(CO)(5) with Li[Ph2P(O)NP(O)Ph-2] afforded the cryptate Li[Re-2(CO)(6)]{mu-Ph2P(O)NP(O)Ph-2-kappa O-2,O'}(3)]; whereas K[Ph2P(O)NP(O)Ph-2] reacted with ReBr(CO)(5) to give K[Re-2(CO)(6){mu-Ph2P(O)NP(O)Ph-2-kappa O-2,O'}{Ph2P(O)NP(O)Ph-2-kappa O-2,O'}(2)]. Other chalcogen ligands' salts M[Ph2P(E)NP(E)Ph-2], E = Se and S. M = K and Li gave dirhenium carbonyls with bromido and Ph2P(E)NP(E)Ph-2, E = Se or S bridges upon reaction with ReBr(CO)(5). (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.08.011
• 作为产物：
  描述：

  五羰基溴铼(I) 、 potassium bis(diphenylselenophosphoryl)amide 以 甲苯 为溶剂， 以73%的产率得到(tetracarbonyl)(tetraphenylimidodiselenophosphinato-κ2Se,Se')rhenium
  参考文献：
  名称：

  Six-membered tetracarbonylmanganese(I) and -rhenium(I) metalacycles containing the [Ph2P(Se)NP(Se)Ph2] ligand: solution and solid state characterization

  摘要：

  The halocarbonyls BrM(CO)(5), M=Mn and Re, were reacted with the KN(SePPh2)(2) salt in equimolar amounts; the reactions were thermally carried out and resulted in the generation of the hexacoordinated isostructural complexes [M(CO)(4){Ph2P(Se)NP-(Se)Ph-2-Se,.Se'}] with a twist MSePNPSe ring conformation. Complexes' characterizations were achieved by IR, mass, NMR (H-1, C-13, (31)p, Se-77) spectroscopies, and by single-crystal X-ray diffraction. (C) 2004 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2004.06.013