| 211733-23-2

• CAS: 211733-23-2
• 化学式: C₉H₁₂Nd₂O₁₅
• 分子量: 648.665
• InChiKey: IIBCWWRKJNFFHG-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  羟基乙酸 、 neodymium(III) formate 以 水 为溶剂， 生成
  参考文献：
  名称：

  A novel family of lanthanide complexes associating two ligands, glycolate and carbonate. Synthesis and characterization of Ln2 (H3C2O3) 4 (CO3) with Ln (III) = La, Ce and Nd

  摘要：

  New lanthanide complexes involving the two ligands, glycolate and carbonate, have been prepared, as a pure phase, by reacting an aqueous suspension of the corresponding lanthanide formate and glycolic acid in closed reactor, under autogeneous pressure at 200 degrees C for one month. The structure of these compounds was determined from single-crystal X-ray method on neodymium complex. It crystallizes in the monoclinic system (space group P2(1)/n) with a three-dimensional framework structure. The coordination scheme of the two independent neodymium atoms is built up by 9 or 10 oxygen atoms from both glycolate and carbonate ligands. The carbonate group acts as a bismonodentate, bischelating ligand. One glycolate is bischelating while the three latter are chelating and monodentate. Infrared spectrum and thermogravimetric analysis of this family are also presented. A tentative explanation of its synthesis will be briefly discussed. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00012-6