| 1233881-97-4

• CAS: 1233881-97-4
• 化学式: C₂₉H₂₀IMnO₄P₂Se
• 分子量: 755.225
• InChiKey: AQAOOGGRLPMJHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 Na 作用下， 以 tetrahydrofuran 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Se−Se Bond Breaking of Polyselenides Containing Pendant Diphosphine Complexes of Manganese(I)

  摘要：

  Reaction of [Mn(CO)(4){(PPh2)(2)CH}] (1) with half an equivalent of dipiperidinotetraselane affords the tetraselenide compound [(CO)(4)Mn{(PPh2)(2)C-Se-4-C(PPh2)(2)}Mn(CO)(4)] (2-Se-4), which, upon treatment with KOH, is transformed into the corresponding triselenide and diselenide derivatives 2-Se-3 and 2-Se-2. Full or partial protonation of the methanide carbon atoms can he accomplished by reaction of the above compounds with HBF4, whereas treatment of 2-Se-2 with I-2 gives rise to the formation of the selenelyl iodide derivative [Mn(CO)(4){(PPh2)(2)C-Se-I}] (5).

  DOI：

  10.1021/om100229q
• 作为产物：
  描述：

  、 碘 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Se−Se Bond Breaking of Polyselenides Containing Pendant Diphosphine Complexes of Manganese(I)

  摘要：

  Reaction of [Mn(CO)(4){(PPh2)(2)CH}] (1) with half an equivalent of dipiperidinotetraselane affords the tetraselenide compound [(CO)(4)Mn{(PPh2)(2)C-Se-4-C(PPh2)(2)}Mn(CO)(4)] (2-Se-4), which, upon treatment with KOH, is transformed into the corresponding triselenide and diselenide derivatives 2-Se-3 and 2-Se-2. Full or partial protonation of the methanide carbon atoms can he accomplished by reaction of the above compounds with HBF4, whereas treatment of 2-Se-2 with I-2 gives rise to the formation of the selenelyl iodide derivative [Mn(CO)(4){(PPh2)(2)C-Se-I}] (5).

  DOI：

  10.1021/om100229q