cis-Pt(C.tplbond.ruthenocenyl)(C6H4OMe-p)(1,2-bis(diphenylphosphino)ethane) | 174967-15-8

• 英文名称: cis-Pt(C.tplbond.ruthenocenyl)(C6H4OMe-p)(1,2-bis(diphenylphosphino)ethane)
• CAS: 174967-15-8
• 化学式: C₄₅H₄₀OP₂PtRu
• 分子量: 954.91
• InChiKey: NLLAPDNIBRABSB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  cis-Pt(C.tplbond.ruthenocenyl)(C6H4OMe-p)(1,2-bis(diphenylphosphino)ethane) 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以37%的产率得到(C5H5)Ru(C5H4C.tplbond.CC6H4OMe-p)
  参考文献：
  名称：

  Preparation and some properties of Pt(II) ruthenocenylacetylide complexes

  摘要：

  Ruthenocenylacetylene reacted with trans-PtI(C(6)H(4)X-p)(PPh(3))(2) (X = H, Me, OMe, Cl or CO(2)Me) in the presence of CuI in diethylamine-CH2Cl2 to give the Pt(II) ruthenocenylacetylide complexes, trans-Pt(C=CRc) (C(6)H(4)X-p)(PPh(3))(2) with a good yield. Similarly, cis-Pt(C=CRc)(C(6)H(4)OMe-p)(dppe) was prepared. The structure of trans-Pt(C=CRc)(C(6)H(4)CO(2)Et-p)(PPh(3))(2) was determined by single-crystal X-ray diffraction. No reaction of the trans isomers with DDQ or AgBF4 took place, while the cis isomer was oxidized with AgBF4 to give the coupling products RcC=CC(6)H(5)OMe-p with a low yield. The oxidation of the cis isomer with iodine occurred on the Pt atom to afford p-MeOC(6)H(4)I and PtI2(dppe) as the main products.

  DOI：

  10.1016/0022-328x(95)05815-7
• 作为产物：
  描述：

  trans-Pt(C.tplbond.ruthenocenyl)(PPh3)2C6H4OMe-p 、 1,2-双(二苯基膦)乙烷 以 not given 为溶剂， 以83.5%的产率得到cis-Pt(C.tplbond.ruthenocenyl)(C6H4OMe-p)(1,2-bis(diphenylphosphino)ethane)
  参考文献：
  名称：

  Preparation and some properties of Pt(II) ruthenocenylacetylide complexes

  摘要：

  Ruthenocenylacetylene reacted with trans-PtI(C(6)H(4)X-p)(PPh(3))(2) (X = H, Me, OMe, Cl or CO(2)Me) in the presence of CuI in diethylamine-CH2Cl2 to give the Pt(II) ruthenocenylacetylide complexes, trans-Pt(C=CRc) (C(6)H(4)X-p)(PPh(3))(2) with a good yield. Similarly, cis-Pt(C=CRc)(C(6)H(4)OMe-p)(dppe) was prepared. The structure of trans-Pt(C=CRc)(C(6)H(4)CO(2)Et-p)(PPh(3))(2) was determined by single-crystal X-ray diffraction. No reaction of the trans isomers with DDQ or AgBF4 took place, while the cis isomer was oxidized with AgBF4 to give the coupling products RcC=CC(6)H(5)OMe-p with a low yield. The oxidation of the cis isomer with iodine occurred on the Pt atom to afford p-MeOC(6)H(4)I and PtI2(dppe) as the main products.

  DOI：

  10.1016/0022-328x(95)05815-7