fac-[Mo(CO)3(η(2)-Ph2PN(iPr)PPh(C3HN2Me2))(MeCN)] | 150344-89-1

• 英文名称: fac-[Mo(CO)3(η(2)-Ph2PN(iPr)PPh(C3HN2Me2))(MeCN)]
• CAS: 150344-89-1
• 化学式: C₃₁H₃₂MoN₄O₃P₂
• 分子量: 666.508
• InChiKey: DPOHXZHSMXKLJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  fac-[Mo(CO)3(η(2)-Ph2PN(iPr)PPh(C3HN2Me2))(MeCN)] 在 Ph₃P 作用下， 以 苯 为溶剂， 以81%的产率得到mer-{Mo(CO)3(PPh3)(P(Ph)2NHCH(CH3)2P(N2C3H(CH3)2))}
  参考文献：
  名称：

  Organometallic chemistry of diphosphazanes

  摘要：

  The reaction of fac-[Mo(CO)3(MeCN)3] with the unsymmetrical diphosphazane Ph2PN(iPr)P(Ph)(DMP) (L) gives the complex fac-[Mo(CO)3(MeCN)(L)] (2) in almost quantitative yield. The structure of the complex has been determined by an X-ray diffraction study. The compound reacts with PR3 (where R = Ph, OPh) to give fac-[Mo(CO)3(PR3)(L)] (3a, 4a), which undergoes an intramolecular isomerization to afford mer-[Mo(CO)3(PR3)(L)] (3b, 4b). Synthesis of cis-[Mo(CO)4(L)] (1) and fac-[MO(CO)3L] (2a) and their spectroscopic data are also reported.

  DOI：

  10.1016/0022-328x(93)83236-o
• 作为产物：
  描述：

  Ph2PN(CHMe2)PPh(N2C3HMe2-3,5) 、 fac-[Mo(CO)3(acetonitrile)3] 以 乙腈 为溶剂， 以77%的产率得到fac-[Mo(CO)3(η(2)-Ph2PN(iPr)PPh(C3HN2Me2))(MeCN)]
  参考文献：
  名称：

  Organometallic chemistry of diphosphazanes

  摘要：

  The reaction of fac-[Mo(CO)3(MeCN)3] with the unsymmetrical diphosphazane Ph2PN(iPr)P(Ph)(DMP) (L) gives the complex fac-[Mo(CO)3(MeCN)(L)] (2) in almost quantitative yield. The structure of the complex has been determined by an X-ray diffraction study. The compound reacts with PR3 (where R = Ph, OPh) to give fac-[Mo(CO)3(PR3)(L)] (3a, 4a), which undergoes an intramolecular isomerization to afford mer-[Mo(CO)3(PR3)(L)] (3b, 4b). Synthesis of cis-[Mo(CO)4(L)] (1) and fac-[MO(CO)3L] (2a) and their spectroscopic data are also reported.

  DOI：

  10.1016/0022-328x(93)83236-o

文献信息

• Babu, Ruppa P. K.; Krishnamurthy, Setharampattu S.; Nethaji, Munirathinam, Organometallics, 1995, vol. 14, # 4, p. 2047 - 2056
  作者：Babu, Ruppa P. K.、Krishnamurthy, Setharampattu S.、Nethaji, Munirathinam

  DOI：——

  日期：——