| 887280-91-3

• CAS: 887280-91-3
• 化学式: C₁₇H₃₂B₁₀NOP
• 分子量: 405.531
• InChiKey: WPNJLFUPKCPBRH-ITBXRFCXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tetrakis(dimethylamido)titanium(IV) 、 以 甲苯 为溶剂， 以58%的产率得到[σ:σ-i-Pr2NP(O)(C9H6)(C2B10H10)]Ti(NMe2)2(HNMe2)
  参考文献：
  名称：

  Pentavalent vs Trivalent Phosphorus-Bridged Ligands. Synthesis and Structural Characterization of Unexpected Group 4 Metal Complexes Incorporating an Indenylide Unit, [σ:σ-ⁱPr₂NP(O)(C₉H₆)(C₂B₁₀H₁₀)]M(NR₂)₂

  摘要：

  Treatment of (Pr2NP)-Pr-i(C9H7)(C2B10H11) with excess 30% hydrogen peroxide in toluene gave the corresponding pentavalent phosphorus-bridged indenyl-carboranyl compound (Pr2NP)-Pr-i(O)(C9H7)(C2B10H11) (2). The equimolar reaction of 2 with M(NR2)(4) in toluene at room temperature afforded unexpected group 4 metal amides incorporating an indenylide unit, [sigma:sigma-(Pr2NP)-Pr-i(O)(C9H6)(C2B10H10)]M(NR2)(2)(L) (R = Me, L = HNMe2, M = Ti (3), Zr (4), Hf (5); R = Et, L = THF, M = Hf (6)). The formation of these new types of group 4 metal complexes was ascribed to the high oxophilicity of the M4+ ions. These new complexes were fully characterized by various spectroscopic techniques, elemental analyses, and single-crystal X-ray diffraction studies (except for 5).

  DOI：

  10.1021/om060082l
• 作为产物：
  描述：

  、 双氧水 以 水 、 甲苯 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  Pentavalent vs Trivalent Phosphorus-Bridged Ligands. Synthesis and Structural Characterization of Unexpected Group 4 Metal Complexes Incorporating an Indenylide Unit, [σ:σ-ⁱPr₂NP(O)(C₉H₆)(C₂B₁₀H₁₀)]M(NR₂)₂

  摘要：

  Treatment of (Pr2NP)-Pr-i(C9H7)(C2B10H11) with excess 30% hydrogen peroxide in toluene gave the corresponding pentavalent phosphorus-bridged indenyl-carboranyl compound (Pr2NP)-Pr-i(O)(C9H7)(C2B10H11) (2). The equimolar reaction of 2 with M(NR2)(4) in toluene at room temperature afforded unexpected group 4 metal amides incorporating an indenylide unit, [sigma:sigma-(Pr2NP)-Pr-i(O)(C9H6)(C2B10H10)]M(NR2)(2)(L) (R = Me, L = HNMe2, M = Ti (3), Zr (4), Hf (5); R = Et, L = THF, M = Hf (6)). The formation of these new types of group 4 metal complexes was ascribed to the high oxophilicity of the M4+ ions. These new complexes were fully characterized by various spectroscopic techniques, elemental analyses, and single-crystal X-ray diffraction studies (except for 5).

  DOI：

  10.1021/om060082l