Reaction of Mo(SBut)4 or Mo(SBut)2(CNBut)4 with CuBr (CNBut)3 or ‘Pd(CNBut)2’ gives mixed d4–d10 bimetal compounds; X-ray crystallographic studies have confirmed the presence of a highly delocalized MoS2Cu core in two conformational isomers of (ButNC)4Mo(µ-SBut)2CuBr.
Mo(SBu t)4或Mo(SBu t)2(CNBu t)4与CuBr(CNBu t)3或'Pd(CNBu t)2 '的反应得到混合的d 4 -d 10双
金属化合物。X射线晶体学研究已证实高度离域的MoS存在2
铜芯在(BU两种构象异构体吨NC)4的Mo(μ -SBu吨)2的CuBr。