hexachlororhenate(V) anion | 31484-74-9

• 英文名称: hexachlororhenate(V) anion
• CAS: 31484-74-9
• 化学式: Cl₆Re
• 分子量: 398.925
• InChiKey: AUGJFLUZJWNGRJ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  4.13
• 重原子数：
  7.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  rhenium hexachloride 在 (TBA)BF₄ 作用下， 以 二氯甲烷 为溶剂， 生成 hexachlororhenate(V) anion
  参考文献：
  名称：

  The preparation and optical charge transfer spectrum of the hexachlororhenium(V) anion

  摘要：

  A convenient synthesis of the relatively poorly studied pentavalent complex anion [RCl6]1- as the tetra-butyl ammonium salt is reported. The complex has been characterised by electrochemical and spectroscopic measurements. The electrode potentials of [ReCl6]1- (Re(V/IV) and Re(IV/III) in CH2Cl2 correspond with those of the [ReCl6]2- ion. The solution electronic absorption spectrum is dominated by two intense Cl to Re(V) charge transfer manifolds which are readily assigned to Laporte-allowed transitions. These features are more accessible than in other d2 chlorides studied previously.

  DOI：

  10.1016/s0020-1693(00)90387-6

文献信息

• Yao, Qin; Maverick, Andrew W., Inorganic Chemistry, 1988, vol. 27, # 10, p. 1669 - 1670
  作者：Yao, Qin、Maverick, Andrew W.

  DOI：——

  日期：——