rhenium dichloro(1,1,1,2,2,6,6,7,7,7-decafluoro-3,5-heptadionate)(triphenylphosphine oxide)(triphenylphosphine) | 1364512-87-7

• 英文名称: rhenium dichloro(1,1,1,2,2,6,6,7,7,7-decafluoro-3,5-heptadionate)(triphenylphosphine oxide)(triphenylphosphine)
• CAS: 1364512-87-7
• 化学式: C₄₃H₃₁Cl₂F₁₀O₃P₂Re
• 分子量: 1104.76
• InChiKey: ICLVLEKLRDBUGK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三苯基膦 以 双氧水 、 苯 为溶剂， 生成 rhenium dichloro(1,1,1,2,2,6,6,7,7,7-decafluoro-3,5-heptadionate)(triphenylphosphine oxide)(triphenylphosphine)
  参考文献：
  名称：

  New rhenium(III) complexes with fluorinated β-diketones

  摘要：

  Five new rhenium(III) complexes of the general formula ReCl2(RFCOCHCORF)(PPh3)(OPPh3), where R-F = CF3 (I), C2F5 (II), C3F7 (III), C4F9 (IV), and CF3CFOC3F7 (V), were synthesized. The known rhenium(V) complex ReOCl2(OC2H5)(PPh3)(2), which can readily be obtained from metallic rhenium, was used as a precursor. Two polymorphous modifications of compound I were found and studied by X-ray diffraction analysis. The thermal properties of the synthesized complexes were characterized by the DTA-TG method. DOI: 10.1134/S1070328412030037

  DOI：

  10.1134/s1070328412030037