[Co(dimethylglyoximato)2(pyridine)(4-MeC6H4SO2)] | 769858-13-1

• 英文名称: [Co(dimethylglyoximato)2(pyridine)(4-MeC6H4SO2)]
• CAS: 769858-13-1
• 化学式: C₂₀H₂₆CoN₅O₆S
• 分子量: 523.516
• InChiKey: LRGFXIUDKVYFIJ-NMBSQECASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  S-benzyl 4-methylbenzenethiosulfonate 、 trans-bis(dimethylglyoximato)(pyridine)benzylcobalt(III) 以 氯仿 为溶剂， 生成 [Co(dimethylglyoximato)2(pyridine)(4-MeC6H4SO2)]
  参考文献：
  名称：

  Gupta; Oberoi; Mandal, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2001, vol. 40, # 9, p. 986 - 988

  摘要：

  DOI：

文献信息

• Organocobaloximes in organic synthesis an unusual radical-dependent five-member cyclization
  作者：Indira Das、Shantanu Chowdhury、Krishnan Ravikumar、Sujit Roy、Bhagawan Dass Gupta

  DOI：10.1016/s0022-328x(96)06801-5

  日期：1997.4

  Visible light photolysis of organocobaloximes R'C=C[CH2](3)-Co-III(dmgH)(2)Py 1-3 (R' = Ph, TMS, H) with radical trapping agents ArSO2Cl (Ar = Ph, 4-MeC6H4, 4-OMeC6H4, 4-BrC6H4, 6ClC(6)H(4)) and MeSO2Cl afford rearranged or non-rearranged organic products depending on the R' group. 2-Phenylcyclopentenyl sulfones 4a-4f have been obtained exclusively in the case of cobaloxime 1. (C) 1997 Elsevier Science S.A.