(BDI)SnCl | 334719-94-7

• 英文名称: (BDI)SnCl
• CAS: 334719-94-7
• 化学式: C₂₉H₄₁ClN₂Sn
• 分子量: 571.821
• InChiKey: JKKNJNUMEVWEIQ-VCGBEGQOSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (BDI)SnCl 、 lithium diisopropyl amide 以 甲苯 为溶剂， 以32%的产率得到[[N(2,6-iPr2C6H3)C(Me)]2CH]SnN(CH(CH3)2)2]
  参考文献：
  名称：

  Synthesis and reactivity of tin amide complexes

  摘要：

  A terminal tin amide and a terminal tin anilide complex, (BDI)SnN(iPr(2)) and (BDI)SnN(H)Ar (Ar = 2,6-(i)Pr(2)C(6)H(3)), respectively, have been synthesized utilizing the bulky beta-diketiminate ligand, [{N(2,6-(i)Pr(2)C(6)H(3))C(Me)}(2)CH] , or BDI, to stabilize the low coordinate divalent tin metal center. Only (BDI) SnN(iPr2) reacts with phenylacetylene to yield (BDI)SnCCPh, but both species react with methyl triflate to give (BDI)SnOTf and carbon dioxide, resulting in the formation of (BDI)SnOC(O)N(iPr(2)) and (BDI)SnOC(O)N(H) Ar. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.009