[bis(triphenyl)phosphoranylydenammonium][AuCl(CCC6H4CCH)] | 515159-12-3

• 英文名称: [bis(triphenyl)phosphoranylydenammonium][AuCl(CCC6H4CCH)]
• CAS: 515159-12-3
• 化学式: C₁₀H₅AuCl*C₃₆H₃₀NP₂
• 分子量: 896.158
• InChiKey: MZSUTIRWAPBVHW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(bis(triphenyl)phosphoranylydenammonium)[Au(acetylacetonate)2]] 、 [bis(triphenyl)phosphoranylydenammonium][AuCl(CCC6H4CCH)] 以 二氯甲烷 为溶剂， 以93%的产率得到[bis(triphenyl)phosphoranylydenammonium]3[Au(CCC6H4CCAuCl)2]
  参考文献：
  名称：

  The first anionic arenediethynylgold(I) complexes

  摘要：

  We report synthetic methods for the preparation of mono-, di-, tri- and polyanionic alkynylgold(l) complexes, derived from diethynylarenes. The reaction between PPN[Au(acac)(2)] and 1,3-diethynylbenzene [HC drop C(mphen)C drop CH] (1:1 M ratio) afforded the polymeric complex (PPN)(n)[Au{C drop C(mphen)C drop C}](n), (1) while the monomeric complexes (PPN)[Au{C-C(Ar)C-CH}(2)] [Ar = mphen (2), mes (3)] resulted when the same dialkyne or 1,3-diethynylmesitylene [HC drop C(mes)C drop CH] were used in a 1:2 M ratio. Complexes PPN[XAuC drop C(Ar)C drop CH] [Ar = mphen, X = Cl (4), Ar = mes, X = Cl (5), SCN (6)] were obtained from the metathesis reactions between complexes 2 or 3 and the appropriate PPN[AuX2] salts. The C drop CH groups in complexes 2 or 4 are acidic enough as to react with [Au(acac)PPh3] (1:2) or with PPN[Au(acac)(2)] (1:1) to give complexes PPN[AufC drop C(mphen)C drop CAuPPh3)(2)] (7) or (PPN)(3)[Au{C drop C(mphen)C drop CAuCl}(2)] (8), respectively. Complexes (PPN)2[XAuC drop C(Ar)C drop CAuX)] [Ar=mphen, X = Cl (9); Ar = mes, X = Cl (10), SCN (11)] have been prepared by reacting [Ph3PAuC drop C(mphen)C drop CAuPPh3] with PPN[AUCl(2)](1:2) (9) or [AuC drop C(mes)C drop CAu](n) with the appropriate PPNX (1:2) salt (10, 11). (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01621-2
• 作为产物：
  描述：

  1,3-二乙炔苯 以 二氯甲烷 为溶剂， 生成 [bis(triphenyl)phosphoranylydenammonium][AuCl(CCC6H4CCH)]
  参考文献：
  名称：

  The first anionic arenediethynylgold(I) complexes

  摘要：

  We report synthetic methods for the preparation of mono-, di-, tri- and polyanionic alkynylgold(l) complexes, derived from diethynylarenes. The reaction between PPN[Au(acac)(2)] and 1,3-diethynylbenzene [HC drop C(mphen)C drop CH] (1:1 M ratio) afforded the polymeric complex (PPN)(n)[Au{C drop C(mphen)C drop C}](n), (1) while the monomeric complexes (PPN)[Au{C-C(Ar)C-CH}(2)] [Ar = mphen (2), mes (3)] resulted when the same dialkyne or 1,3-diethynylmesitylene [HC drop C(mes)C drop CH] were used in a 1:2 M ratio. Complexes PPN[XAuC drop C(Ar)C drop CH] [Ar = mphen, X = Cl (4), Ar = mes, X = Cl (5), SCN (6)] were obtained from the metathesis reactions between complexes 2 or 3 and the appropriate PPN[AuX2] salts. The C drop CH groups in complexes 2 or 4 are acidic enough as to react with [Au(acac)PPh3] (1:2) or with PPN[Au(acac)(2)] (1:1) to give complexes PPN[AufC drop C(mphen)C drop CAuPPh3)(2)] (7) or (PPN)(3)[Au{C drop C(mphen)C drop CAuCl}(2)] (8), respectively. Complexes (PPN)2[XAuC drop C(Ar)C drop CAuX)] [Ar=mphen, X = Cl (9); Ar = mes, X = Cl (10), SCN (11)] have been prepared by reacting [Ph3PAuC drop C(mphen)C drop CAuPPh3] with PPN[AUCl(2)](1:2) (9) or [AuC drop C(mes)C drop CAu](n) with the appropriate PPNX (1:2) salt (10, 11). (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01621-2