[Cu(2,2'-biimidazole)2(H2O)](SiF6)*H2O | 1210345-44-0

• 英文名称: [Cu(2,2'-biimidazole)2(H2O)](SiF6)*H2O
• CAS: 1210345-44-0
• 化学式: C₁₂H₁₄CuN₈O*F₆Si*H₂O
• 分子量: 509.933
• InChiKey: CFZZQYQWNBFUMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(2,2'-biimidazole)2(H2O)](SiF6)*H2O 以 neat (no solvent, solid phase) 为溶剂， 生成 氟硅酸铜
  参考文献：
  名称：

  Synthesis, characterization and crystal structures of supramolecular complexes of copper(II)(2,2′-biimidazole) induced by inorganic counter anions

  摘要：

  Four new complexes [Cu(H(2)biim)(2)(H(2)O)](NO(3))(2) (1), [Cu(H(2)biim)(2)](ClO(4))(2)center dot 2DMSO (2), [Cu(H(2)biim)(2)] [I(0.36)center dot(NO(3))(0.64)](2) (3) and {[Cu(H(2)biim)(2)(H(2)O)](SiF(6))}center dot H(2)O (4) (H(2)biim = 2,2'-biimdazole, DMSO = dimethyl sulfoxide) have been synthesized and characterized by X-ray diffraction. The different inorganic anions NO(3)(-), ClO(4)(-), [I(0.36)center dot(NO(3))(0.64)](-) and SiF(6)(2-) in these complexes lead to different 3D structures. Among them, complex 3 has an interesting 3D porous structure with two [I(0.36)center dot(NO(3))(0.64)](-) ions as guests in the cavity. Compound 4 was obtained by the reaction of Cu(BF(4))(2) with H(2)biim in water in glass bottle. The robust hydrogen bond of typeV R(2)(1)(7) played a key role in the formation of SiF(6)(2-) in complex 4. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.05.052
• 作为产物：
  描述：

  联咪唑 、 copper(II) tetrafluroborate hexahydrate 、 silica gel 以 水 为溶剂， 生成 [Cu(2,2'-biimidazole)2(H2O)](SiF6)*H2O
  参考文献：
  名称：

  Synthesis, characterization and crystal structures of supramolecular complexes of copper(II)(2,2′-biimidazole) induced by inorganic counter anions

  摘要：

  Four new complexes [Cu(H(2)biim)(2)(H(2)O)](NO(3))(2) (1), [Cu(H(2)biim)(2)](ClO(4))(2)center dot 2DMSO (2), [Cu(H(2)biim)(2)] [I(0.36)center dot(NO(3))(0.64)](2) (3) and {[Cu(H(2)biim)(2)(H(2)O)](SiF(6))}center dot H(2)O (4) (H(2)biim = 2,2'-biimdazole, DMSO = dimethyl sulfoxide) have been synthesized and characterized by X-ray diffraction. The different inorganic anions NO(3)(-), ClO(4)(-), [I(0.36)center dot(NO(3))(0.64)](-) and SiF(6)(2-) in these complexes lead to different 3D structures. Among them, complex 3 has an interesting 3D porous structure with two [I(0.36)center dot(NO(3))(0.64)](-) ions as guests in the cavity. Compound 4 was obtained by the reaction of Cu(BF(4))(2) with H(2)biim in water in glass bottle. The robust hydrogen bond of typeV R(2)(1)(7) played a key role in the formation of SiF(6)(2-) in complex 4. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.05.052