Na[Ru(cyclopentadienyl)(PPh3)(maleonitriledithiolate)] | 163491-57-4

• 英文名称: Na[Ru(cyclopentadienyl)(PPh3)(maleonitriledithiolate)]
• CAS: 163491-57-4
• 化学式: C₂₇H₂₀N₂PRuS₂*Na
• 分子量: 591.635
• InChiKey: VEYSPLMABDKTEH-NPDUFXBMSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Na[Ru(cyclopentadienyl)(PPh3)(maleonitriledithiolate)] 、 四乙基氯化铵 以 甲醇 、 水 为溶剂， 以40%的产率得到cyclopenta-1,3-diene;(Z)-1,2-dicyanoethene-1,2-dithiolate;ruthenium(2+);tetraethylazanium;triphenylphosphane
  参考文献：
  名称：

  Prasad, R.; Prasad, S.; Agrwala, U. C., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1995, vol. 25, p. 1493 - 1506

  摘要：

  DOI：
• 作为产物：
  描述：

  二(三苯基膦)环戊二烯基氯化钌(II) 、 disodium maleonitriledithiolato 以 甲醇 为溶剂， 以50%的产率得到Na[Ru(cyclopentadienyl)(PPh3)(maleonitriledithiolate)]
  参考文献：
  名称：

  Prasad, R.; Prasad, S.; Agrwala, U. C., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1995, vol. 25, p. 1493 - 1506

  摘要：

  DOI：

文献信息

• Synthesis, spectral and electrochemical aspects of maleonitriledithiolate and dibenzyldithiomaleonitrile complexes of cyclopentadienylruthenium(II)
  作者：Rajendra Prasad

  DOI：10.1016/0022-328x(94)05034-9

  日期：1995.1

  Complexes [RuCp(PPh(3)S2C2(CN)(2)}](-) (1), [Ru(2)Cp(2)(PPh(3))(4)S2C2(CN)(2)}] (2) and [RuCp(PPh(3))S-2(CH2C6H5)(2)C-2(CN)(2)}](+) (3) have been synthesized by the reaction of [CpRu(PPh(3))(2)Cl] with S2C2(CN)(2)(2-) or (C6H5CH2)(2)S2C2(CN)(2)] in MeOH. The complex [RuCp(PPh(3))S-2(CH2-C6H5)(2)C-2(CN)(2)}](+) when further reacted with [CpRu(PPh(3))(2)Cl] formed a dinuclear complex [Ru(2)Cp(2)(PPh(3))(3)S-2(CH2C6H5)(2)C-2(CN)(2)}](2+) (4). All these complexes have been characterized by their physical and spectral (IR; H-1 P-31 NMR and visible spectral data. S2C2(CN)(2)(2-) has been found to introduce a low lying MLCT absorption in the electronic spectra of its complexes. In CV scan these complexes exhibit an extended series of one electron transfer reactions. The metal-centred oxidation waves of the complexes have been correlated with the pi acidity of ligands.