{(ruthenium)2H(carbonyl)5(μ-(isopropoxy)2PN(Et)P(isopropoxy)2)2} hexafluorophosphate | 145631-94-3

• 英文名称: {(ruthenium)2H(carbonyl)5(μ-(isopropoxy)2PN(Et)P(isopropoxy)2)2} hexafluorophosphate
• CAS: 145631-94-3；108389-41-9
• 化学式: C₃₃H₆₇N₂O₁₃P₄Ru₂*F₆P
• 分子量: 1170.9
• InChiKey: PJXOLIXHJJMZQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {(ruthenium)2H(carbonyl)5(μ-(isopropoxy)2PN(Et)P(isopropoxy)2)2} hexafluorophosphate 在 base 作用下， 以 not given 为溶剂， 生成 {Ru2(μ-CO)(CO)4(μ-(i-PrO)2PN(Et)P(Oi-Pr)2)2}
  参考文献：
  名称：

  Protonation of a series of diphosphazane- and diphosphine-bridged derivatives of iron and ruthenium: dependence of the nature of the hydride ligand on the metal and the bridging diphosphorus ligand

  摘要：

  DOI：

  10.1016/0022-328x(87)85033-7
• 作为产物：
  描述：

  hexafluorophosphoric acid 、 {Ru2(μ-CO)(CO)4(μ-(i-PrO)2PN(Et)P(Oi-Pr)2)2} 以 not given 为溶剂， 生成 {(ruthenium)2H(carbonyl)5(μ-(isopropoxy)2PN(Et)P(isopropoxy)2)2} hexafluorophosphate
  参考文献：
  名称：

  Protonation of a series of diphosphazane- and diphosphine-bridged derivatives of iron and ruthenium: dependence of the nature of the hydride ligand on the metal and the bridging diphosphorus ligand

  摘要：

  DOI：

  10.1016/0022-328x(87)85033-7

文献信息

• Synthesis and reactivity of the formally co-ordinatively unsaturated diruthenium hydride [Ru₂(µ-H)(µ-CO)(CO)₃{µ-(PrⁱO)₂PNEtP(OPrⁱ)₂}₂]⁺and its co-ordinatively saturated parent [Ru₂H(CO)₅{µ-(PrⁱO)₂PNEtP(OPrⁱ)₂}₂]⁺
  作者：Karen J. Edwards、John S. Field、Raymond J. Haines、Beverley D. Homann、Mark W. Stewart、Jorg Sundermeyer、Stephen F. Woollam

  DOI：10.1039/dt9960004171

  日期：——

  [Ru2(µ-H)(µ-CO)(CO)3(µ-etipdp)2]PF6 on reaction with systems of the type X′Y′ and X″Y″Z″ except that, for terminal alkynes such as PhCCH, alkenylcarbonyl-bridged products, e.g.[Ru2µ-η2-OC(CHCHPh)}(CO)4(µ-etipdp)2]PF6, are produced. The crystal structures of the following compounds were determined : [Ru2(µ-H)(µ-CO)(CO)3(µ-etipdp)2]PF6, [Ru2(µ-I)H(µsb-CO)(CO)2(µ-etipdp)2], [Ru2µ-N(CHPh)}(CO)4(µ-etipdp)2]PF6,

  配位不饱和物质的质子化[Ru 2（µ SB -CO）2（CO）2（µ-etipdp）2 ] [SB =半桥，etipdp =（Pr i O）2 PNEtP（OPr i）2 ]通过非配位共轭碱（例如HBF 4 ·OEt 2）的酸产生[Ru 2（µ-H）（µ-CO）（CO）3（µ-etipdp）2 ] +，其确定为X PF 6的晶体射线衍射–盐同时包含桥连羰基和桥连氢化物配体。这种阳离子种类非常容易受到中性和阴离子亲核试剂的攻击，从而提供多种产品类型。例如，其与阴离子X的反应-其能够作为单齿桥连配体和其优先采用的起作用的封闭桥接协调模式，例如卤化物和硫化氢离子的类型的所提供的产品的[Ru 2（μ-X）H （μ SB -CO）（CO）2（μ-etipdp）2 ]（X =氯，溴，I，SH，等等），从羰基的由亲核取代得到的。另一方面，阴离子亲核试剂如H-和CN - ，得到加成产物的类型的[Ru 2 HX（CO）
• Protonation of diphosphazane ligand-bridged derivatives of diruthenium nonacarbonyl by protic acids with co-ordinating and non-co-ordinating conjugate bases
  作者：John S. Field、Raymond J. Haines、Eric Minshall、Clifford N. Sampson、J�rg Sundermeyer、Stephen F. Woollam

  DOI：10.1039/dt9920002629

  日期：——

  Protonation of the diphosphazane ligand-bridged derivatives [Ru2(mu-CO)(CO)4mu-(RO)2PN(Et)P(OR)2}2] (R = Me or Pr(i)) by HBF4 or HPF6 leads to the formation of the cationic hydrido products [Ru2H(CO)5mu-(RO)2PN(Et)P(OR)2}2]+ in which the hydride ligand is co-ordinated terminally. On the other hand, protonation of these species with strong protic acids HA having conjugate bases A- with co-ordinating properties [A- = Cl-, Br-, NO3-, FB(O)OH- or CF3CO2-] gives rise to products of the type [Ru2A(CO)5mu-(RO)2PN(Et)P(OR)2}2]+ and/or [Ru2(mu-A)(CO)4mu-(RO)2PN(Et)P(OR)2}2]+. Weak acids HA (A- = SPh- or HCO3-) also afford these types of products but the presence of a strong acid such as HPF6 is necessary. The structures of two of the products [Ru2mu-OB(F)OH}(CO)4mu-(PriO)2PN(Et)P(OPri2}2]BF4 and [Ru2(mu-SPh)(CO)4mu-(MeO)2PN(Et)P(OMe)2}2]PF6 have been established by X-ray crystallography and are discussed as is the fluxional behaviour of the hydrido species [Ru2H(CO)5mu-(RO)2PN(Et)P(OR)2}2]+.
• Synthesis of three-, four-, and five-membered dimetalloheterocyclic compounds by reaction of the hydride [Ru2H(CO)5μ-(RO)2PN(Et)P(OR)22][PF6] (R = Me or Pri) with unsaturated systems of the type XY and X′Y′Z′. Crystal structures of representative examples of the three types of products
  作者：Karen J. Edwards、John S. Field、Raymond J. Haines、Beverley Homann、Jörg Sundermeyer、Stephen F. Woollam

  DOI：10.1016/0022-328x(90)80263-y

  日期：1990.4