μ-(3,6,9,17,20,23-hexamethyl-3,6,9,17,20,23-hexaaza-29,30-dithiolato-13,27-di-tert-butyltricyclo[23.3.1(11.15)]triaconat-1(28),11,13,15(30),25,26-hexaene)μ-chlorodicobalt(II) perchlorate | 390765-95-4

• 英文名称: μ-(3,6,9,17,20,23-hexamethyl-3,6,9,17,20,23-hexaaza-29,30-dithiolato-13,27-di-tert-butyltricyclo[23.3.1(11.15)]triaconat-1(28),11,13,15(30),25,26-hexaene)μ-chlorodicobalt(II) perchlorate
• CAS: 390765-95-4
• 化学式: C₃₈H₆₄ClCo₂N₆S₂*ClO₄
• 分子量: 921.988
• InChiKey: UROQIOCISQVSJO-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  μ-(3,6,9,17,20,23-hexamethyl-3,6,9,17,20,23-hexaaza-29,30-dithiolato-13,27-di-tert-butyltricyclo[23.3.1(11.15)]triaconat-1(28),11,13,15(30),25,26-hexaene)μ-chlorodicobalt(II) perchlorate 、 erythro-2,3-dibromo-3-phenylpropanoic acid 在 三乙胺 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  封装的烯烃的顺式溴化。

  摘要：

  DOI：

  10.1002/anie.200351131

文献信息

• Carboxylate and Alkyl Carbonate Coordination at the Hydrophobic Binding Site of Redox-Active Dicobalt Amine Thiophenolate Complexes
  作者：Berthold Kersting、Gunther Steinfeld

  DOI：10.1021/ic011004n

  日期：2002.3.1

  mixed-valent complexes [(L(Me))Co(II)Co(III)(mu-O(2)CR)](2+) (3, 6, 9) and the fully oxidized Co(III)Co(III) forms [(L(Me))Co(III)(2)(mu-O(2)CR)](3+) (4, 7, 10), respectively. Compounds 3, 6, 9 and 4, 7, 10 refer to acetato-, cinnamato-, and methylcarbonato species, respectively. The Co(II)Co(III) compounds were prepared by comproportionation of the respective Co(II)(2) and Co(III)(2) compounds. The Co(III)Co(III)

  制备了一系列新的全甲基化大环六胺二硫代酚酸酯配体H（2）L（Me）的二甲杂英醇配合物，并在配体结合和氧化态变化的背景下进行了研究。八齿配体是一种有效的双核配体，可支持具有中央N（3）Co（mu-SR）（2）（mu-X）CoN（3）核心结构的生物六面体复合物的形成，从而为基材的配合。乙酰-和肉桂桥联的复合物[（L（Me））Co（II）（2）（mu-O（2）CMe）]（+）（2）和[（L（Me））Co（II） （2）（mu-O（2）CCH = CHPh）]（+）通过mu-Cl络合物[（L（Me））Co（II）（2）（mu-Cl）的反应制备（5） ]（+）（1）与相应的甲醇钠的甲醇溶液。还研究了这些化合物和碳酸甲酯络合物[（L（Me））Co（II）（2）（mu-O（2）COMe）]（+）（8）的电化学性质。所有的配合物在大约200℃经历两次逐步氧化。E（1）（1/2）= +0.22并在E（2）（1/2）=
• Stabilization of a Monomethyl Orthomolybdate in the Binding Pocket of a Dinuclear Cobalt Complex
  作者：Vasile Lozan、Berthold Kersting

  DOI：10.1021/ic0603656

  日期：2006.7.1

  The ability of the dinuclear Co-II complex [(L-Me)Co-2(II)(mu-Cl)](+) [1; (L-Me)(2-) = 3,6,9,17,20,23-hexamethyl-3,6,9,17,20,23- hexaaza-29,30-dithiol-13,27-di-tert-butyltricyclo[23.3.1(11.15)]triaconta-1(28), 11,13,15(30), 25,26-hexaene] to bind tetrahedral oxoanions of the transition metal has been investigated. Two new complexes, [(L-Me)Co-2(II)(mu-MoO4)] (2) and [(L-Me)Co-2(II)(mu-MoO3(OMe))](2)[Mo4O10(OMe)(6)] (3), were prepared by substitution reactions of 1 with (n-Bu4N)(2)-MoO4 in MeCN or with MoO3 center dot 2H(2)O/NEt3 in MeOH. Both compounds were characterized by X-ray crystallography. The dioctahedral complex 2 features a mu(1,3)-bridging MoO42- unit, whereas the cation in 3 hosts an unprecedented mu(1,3)-MoO3(OMe)(-) motif, demonstrating that four-coordinate molybdate esters can be stabilized in the binding pocket of the bowl-shaped [(L-Me)Co-2(II)](2+) complex. The results of IR, UV/vis, and cyclic voltammetry measurements are also reported.