| 1305337-29-4

• CAS: 1305337-29-4
• 化学式: C₂₂H₂₅NNiO₃
• 分子量: 410.135
• InChiKey: GXCHDTOUQWPGST-TXBTUDEPSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  苯酚,2-[[[2,6-二(1-甲基乙基)苯基]亚氨基]甲基]- 在 CH₃C₆H₄CHNCH₂C₆H₅ 作用下， 以 氘代苯 、 苯 为溶剂， 生成 、 (2-((2,6-diisopropylphenyl)iminomethyl)phenoxide)Ni(COCH3)(N-benzyltolualdimine)
  参考文献：
  名称：

  Synthesis of neutral nickel–methyl complexes with monodentate imines and their sequential insertion of carbon monoxide and imine

  摘要：

  Neutral nickel-imine complexes of the form (N boolean AND O)Ni(R)((RN)-N-1=C(H)R-2) (N boolean AND O = salicylaldiminato; R = CH3, Ph; R-1 = alkyl; R-2 = aryl) can be prepared by the reaction of (tmeda)Ni(CH3)(2), imine and the corresponding salicylaldiminato ligand. The addition of carbon monoxide to these complexes lead to the in situ generation of the corresponding nickel-acyl complexes. With N-methyl or N-benzyl substituted imines, these complexes reductively eliminate the phenolic and acyl ligands to generate esters. However, the less sterically encumbered 3,4-dihydroisoquinoline can couple with the nickel-acyl ligand to form 1,2-diamides in high yield. In situ H-1 NMR analysis suggests this reaction occurs via insertion of imine into the nickel-acyl bond to form a nickel-bound amide complex.[GRAPHICS](C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.024