| 848985-49-9

• CAS: 848985-49-9
• 化学式: C₅₄H₄₅Br₂NOReSb₃
• 分子量: 1435.22
• InChiKey: SNSZPFPUBKOPJA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氯仿 、 以 乙醇 、 氯仿 为溶剂， 以3%的产率得到
  参考文献：
  名称：

  Reactions of [ReX5(NO)]2− with triphenylstibine. Spectroscopic investigations of [ReX2(NO)(SbPh3)3], X-ray structures of [ReCl2(NO)(SbPh3)3] and [ReBr2Cl(SbPh3)3] and DFT calculations for [ReCl2(NO)(SbPh3)3]

  摘要：

  The reactions of [NBu4](2)[ReX5(NO)] (X = Cl, Br) with triphenylstibine have been examined and three new rhenium complexes [ReCl2(NO)(SbPh3)(3)] (1), [ReBr2(NO)(SbPh3)(3)] (2) and [ReBr2Cl(SbPh3)(3)] (3) - have been obtained. The last one has been isolated in a low yield during slow recrystallization of the complex 2 from a mixture of chloroform and ethanol. The stibine rhenium nitrosyls have been characterized by IR and UV-vis spectroscopy. The X-ray structures of and 3 have been determined. The geometric parameters of 1 have been examined using the density functional theory (DFT) method. (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.11.028
• 作为产物：
  描述：

  、 三苯基锑 以 乙醇 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  Reactions of [ReX5(NO)]2− with triphenylstibine. Spectroscopic investigations of [ReX2(NO)(SbPh3)3], X-ray structures of [ReCl2(NO)(SbPh3)3] and [ReBr2Cl(SbPh3)3] and DFT calculations for [ReCl2(NO)(SbPh3)3]

  摘要：

  The reactions of [NBu4](2)[ReX5(NO)] (X = Cl, Br) with triphenylstibine have been examined and three new rhenium complexes [ReCl2(NO)(SbPh3)(3)] (1), [ReBr2(NO)(SbPh3)(3)] (2) and [ReBr2Cl(SbPh3)(3)] (3) - have been obtained. The last one has been isolated in a low yield during slow recrystallization of the complex 2 from a mixture of chloroform and ethanol. The stibine rhenium nitrosyls have been characterized by IR and UV-vis spectroscopy. The X-ray structures of and 3 have been determined. The geometric parameters of 1 have been examined using the density functional theory (DFT) method. (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.11.028