[Fe(II)(OEt2)(Si(C6H4PiPr2-2)2(C6H4SAd-2))][tetrakis(3,5-bis(trifluoromethyl)phenylborate)] | 1303610-18-5

• 英文名称: [Fe(II)(OEt2)(Si(C6H4PiPr2-2)2(C6H4SAd-2))][tetrakis(3,5-bis(trifluoromethyl)phenylborate)]
• CAS: 1303610-18-5
• 化学式: C₃₂H₁₂BF₂₄*C₄₈H₆₆FeOPS₂Si
• 分子量: 1701.31
• InChiKey: GRUFGZQUJYTEAK-BEIPSAGUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氮气-15N2 、 [Fe(II)(OEt2)(Si(C6H4PiPr2-2)2(C6H4SAd-2))][tetrakis(3,5-bis(trifluoromethyl)phenylborate)] 在 Co(C₅H₅)2 or Cr(C₆H₆)2 作用下， 以 not given 为溶剂， 生成 [(Fe(Si(C6H4PiPr2-2)2(C6H4SAd-2)))2([(15)N2]dinitrogen)][tetrakis(3,5-bis(trifluoromethyl)phenylborate)]
  参考文献：
  名称：

  Dinitrogen Complexes of Sulfur-Ligated Iron

  摘要：

  We report a unique class of dinitrogen complexes of iron featuring sulfur donors in the ancillary ligand. The ligands utilized are related to the recently studied tris(phosphino)silyl ligands (2-R2PC6H4)(3)Si (R = Ph, iPr) but have one or two phosphine arms replaced with thioether donors. Depending on the number of phosphine arms replaced, both mononuclear and dinuclear iron complexes with dinitrogen are accessible. These complexes contribute to a desirable class of model complexes that possess both dinitrogen and sulfur ligands in the immediate iron coordination sphere.

  DOI：

  10.1021/ja2020907
• 作为产物：
  描述：

  hydrogen tetrakis(3,5-bis(trifluoromethyl)phenyl)borate 、 乙醚 、 [Fe(II)Me(Si(C6H4PiPr2-2)2(C6H4SAd-2))] 以 乙醚 为溶剂， 生成 [Fe(II)(OEt2)(Si(C6H4PiPr2-2)2(C6H4SAd-2))][tetrakis(3,5-bis(trifluoromethyl)phenylborate)]
  参考文献：
  名称：

  Dinitrogen Complexes of Sulfur-Ligated Iron

  摘要：

  We report a unique class of dinitrogen complexes of iron featuring sulfur donors in the ancillary ligand. The ligands utilized are related to the recently studied tris(phosphino)silyl ligands (2-R2PC6H4)(3)Si (R = Ph, iPr) but have one or two phosphine arms replaced with thioether donors. Depending on the number of phosphine arms replaced, both mononuclear and dinuclear iron complexes with dinitrogen are accessible. These complexes contribute to a desirable class of model complexes that possess both dinitrogen and sulfur ligands in the immediate iron coordination sphere.

  DOI：

  10.1021/ja2020907