| 500569-47-1

• CAS: 500569-47-1
• 化学式: C₂₇H₄₉Si₂Y
• 分子量: 518.763
• InChiKey: CEYGDOPCTGNUCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  双(三甲基硅基)甲烷 、 trans-(C5(CH3)5)2Y(CH=CHCH(CH3)2) 以 further solvent(s) 为溶剂， 生成
  参考文献：
  名称：

  Why propene is not polymerized by (Cp*2YH)2: reactions of yttrium alkyl complexes with alkenes produce allyl and vinyl yttrium complexes

  摘要：

  Yttrium alkyl complexes (Cp2YR)-Y-* react with C-H bonds of alkenes to form either yttrium allyl complexes or yttrium vinyl complexes. Less substituted alkenes react faster, consistent with prior alkene coordination. The selectivity of the reaction of (Cp2YR)-Y-* with C-H bonds is allylic CH3 much greater than vinyl C-H much greater than allylic CH2. Propene is readily metallated by (Cp2YR)-Y-* giving the eta(3)-allyl complex (Cp2Y)-Y-*(eta(3)-CH2 - CH - CH2) which does not react further with propene. This explains why (Cp2YR)-Y-* (R = alkyl, H) complexes make poor propene polymerization catalysts. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01771-0