{trans-Rh(PPh3)2(CO)(O2PF2)} | 126979-29-1

• 英文名称: {trans-Rh(PPh3)2(CO)(O2PF2)}
• 英文别名: trans-[Rh(CO)(triphenylphosphine)2(OPOF2)
• CAS: 126979-29-1
• 化学式: C₃₇H₃₀F₂O₃P₃Rh
• 分子量: 756.467
• InChiKey: KKSSCBWRKWULEP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Rh(CO)(triphenylphosphine)2(water)]PF6 以 乙醇 为溶剂， 生成 {trans-Rh(PPh3)2(CO)(O2PF2)}
  参考文献：
  名称：

  Cationic rhodium(I) complexes formed in the reactions of HRh(CO)L3 (L=PPh3, P(OPh)3) complexes with silver(I) salts

  摘要：

  The reactions of HRh(CO)L-3 (L=PPh3, P(OPh)(3)) complexes with AgY (Y=BF4-, CF3SO3-, PF6-) lead to [Rh(CO)(PPh3)(2)(H2O)]Y and [Rh (CO)(P(OPh)(3))(3)]Y compounds. The solvolysis of [Rh(CO)(PPh3)(2)(H2O)]PF6 in ethanol produced a crystalline trans-[Rh(CO)(PPh3)(2)(OPOF2)] complex containing distorted square-planar rhodium center. The different arrangement of OPOF2- ligands found in two crystallographically independent molecules is connected with the presence of intra- and intermolecular C-H...O hydrogen bonds involving both oxygen atoms of each OPOF2- anion. The reaction of [Rh(CO)(P(OPh)(3))(3)]Y (Y=BF4-, PF6-) in solution with CO leads to [Rh(CO)(2)(P(OPh)(3))(3)]Y and with P(OPh)(3) to [Rh(P(OPh)(3))(4)]Y complexes. The [Rh(P(OPh)(3))(4)]PF6 complex was also obtained as a final reaction product of HRh(P(OPh)(3))(4) with AgPF6. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01551-7

文献信息

• Branan, Daniel M.; Hoffman, Norris W.; McElroy, E. Andrew, Inorganic Chemistry, 1991, vol. 30, # 6, p. 1200 - 1207
  作者：Branan, Daniel M.、Hoffman, Norris W.、McElroy, E. Andrew、Prokopuk, Nicholas、Salazar, Anna B.、Robbins, Martha J.、Hill、Webb, Thomas R.

  DOI：——

  日期：——