(2,6-C6H3(CH2P(CF3)2)2)Pt(Cl) | 1000978-27-7

• 英文名称: (2,6-C6H3(CH2P(CF3)2)2)Pt(Cl)
• 英文别名: [(2,6-C6H3(CH2P(CF3)2)2)PtCl]
• CAS: 1000978-27-7
• 化学式: C₁₂H₇ClF₁₂P₂Pt
• 分子量: 671.649
• InChiKey: XPODRJAQUYLGFN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2,6-C6H3(CH2P(CF3)2)2)Pt(Cl) 、 甲基溴化镁 以 乙醚 为溶剂， 以72%的产率得到(2,6-C6H3(CH2P(CF3)2)2)PtMe
  参考文献：
  名称：

  全氟烷基受体钳形配体1,3-（CH（2）P（CF（3））（2））（2）C（6）H（4）的合成和铂配位化学。

  摘要：

  报道了全氟烷基取代的“夹子”型PCP配体1,3-C6H4（CH2P（Rf）2）2（Rf = CF3，C2F5）和铂配位研究（Rf = CF3）的合成。1,3-C6H4（CH2P（CF3）2）2（CF3PCPH）在环境温度下与（cod）Pt（Me）Cl（cod = 1,5-环辛二烯）和（cod）PtMe2反应以提供未金属化的PCPH桥连产物[（CF3PCPH）Pt（Me）Cl] x和顺式-[（CF3PCPH）PtMe2] 2。顺式[[（CF3PCPH）PtMe2] 2是可溶的，并已在光谱和晶体学上进行了表征。这些化合物的热解导致甲烷的损失以及金属化配合物（CF3PCP）PtCl和（CF3PCP）PtMe的形成。用MeMgBr处理（CF3PCP）PtCl为（CF3PCP）PtMe提供了另一种途径。

  DOI：

  10.1021/ic701426u
• 作为产物：
  描述：

  [(1,3-C6H4(CH2P(CF3)2)2)Pt(Me)Cl] 以 间二甲苯 为溶剂， 以94%的产率得到(2,6-C6H3(CH2P(CF3)2)2)Pt(Cl)
  参考文献：
  名称：

  全氟烷基受体钳形配体1,3-（CH（2）P（CF（3））（2））（2）C（6）H（4）的合成和铂配位化学。

  摘要：

  报道了全氟烷基取代的“夹子”型PCP配体1,3-C6H4（CH2P（Rf）2）2（Rf = CF3，C2F5）和铂配位研究（Rf = CF3）的合成。1,3-C6H4（CH2P（CF3）2）2（CF3PCPH）在环境温度下与（cod）Pt（Me）Cl（cod = 1,5-环辛二烯）和（cod）PtMe2反应以提供未金属化的PCPH桥连产物[（CF3PCPH）Pt（Me）Cl] x和顺式-[（CF3PCPH）PtMe2] 2。顺式[[（CF3PCPH）PtMe2] 2是可溶的，并已在光谱和晶体学上进行了表征。这些化合物的热解导致甲烷的损失以及金属化配合物（CF3PCP）PtCl和（CF3PCP）PtMe的形成。用MeMgBr处理（CF3PCP）PtCl为（CF3PCP）PtMe提供了另一种途径。

  DOI：

  10.1021/ic701426u

文献信息

• Acceptor Pincer Coordination Chemistry of Platinum: Reactivity Properties of (^CF₃PCP)Pt(L)⁺ (L = NC₅F₅, C₂H₄)
  作者：Jeramie J. Adams、Navamoney Arulsamy、Dean M. Roddick

  DOI：10.1021/om8008876

  日期：2009.2.23

  Synthetic strategies toward the synthesis of electron-poor pincer complexes ((PCP)-P-CF3)PtH and ((PCP)-P-CF3)Pt(eta(2)-H-2)(+) are described. Metathesis of ((PCP)-P-CF3)PtCl with hydride reagents does not lead to ((PCP)-P-CF3)PtH; ((PCP)-P-CF3)PtCl with KH in tetrahydrofuran (THF) afforded an unusual metallated bimetallic pincer product ((PCP)-P-CF3)Pt[kappa(1)-C,kappa P3-,C,P-2,6-(CHP(CF3)(2))(CH2P(CF3)(2))-C6H3]PtCl, which has been structurally characterized. Chloride abstraction from ((PCP)-P-CF3)PtCl or protonolysis of ((PCP)-P-CF3)PtMe in the presence of H-2 gives the structurally characterized hydride-bridged dimer ((PCP)-P-CF3)Pt}(2)(mu-H)(+). In the presence of trapping ligands H2O, C2H4, or pentafluoropyridine, the corresponding complexes ((PCP)-P-CF3)Pt(L)(+) (L = H2O, C2H4, NC5F5) are cleanly produced and have been structurally characterized. The C2H4 and NC5F5 adducts may be alternatively prepared by methide abstraction from (CF3PCP)PtMe with Ph3C+B(C6F5)(4)(-) in the presence of trapping ligand. Evidence for the transient formation of ((PCP)-P-CF3)PtH from treatment of ((PCP)-P-CF3)PtCl or ((PCP)-P-CF3)Pt(NC5F5)(+) with Et3Si+B(C6F5)(4)(-) is presented. ((PCP)-P-CF3)Pt(C2H4)(+) serves as a catalyst for ethylene hydrogenation (0.30 turnovers h(-1), 70 degrees C) and hydrosilation with Et3SiH (460 turnovers h(-1), RT) and Cl3SiH (5 turnovers h(-1), RT). At elevated temperatures, ((PCP)-P-CF3)Pt(C2H4)(+) also exhibits limited ethylene dimerization activity (0.07 turnovers h(-1), 155 degrees C and 1-butene isomerization (0.9 turnovers h(-1), 80 degrees C).
• Preparation of an unusual fluoroalkyl phosphinoyl chelate complex, {k3-P,C,P,k1-O-(CF3)2PCH2C6H3CH2P(CF3)O}2Pt2
  作者：Jeramie J. Adams、Navamoney Arulsamy、Dean M. Roddick

  DOI：10.1016/j.ica.2008.08.015

  日期：2009.4

  Electron poor cationic complexes [((PCP)-P-CF3)Pt(L)](+) (where L = CO, NC5F5, or acetone) react with H2O in polar solvents via selective hydrolysis of a single P-CF3 substituent to afford the spectroscopically- characterized phosphinoyl-bridged complex k(3)-P,C,P,k(1)-O-(CF3)(2)PCH2C6H3CH2P(CF3)O}(2)Pt-2 (1) in good yield. X-ray diffraction confirms the presence of a six-member Pt-P-O-Pt-P-O ring in a chair conformation. The presumed intermediate aqua complex, ((PCP)-P-CF3)Pt(H2O)(+), is stable in dichloromethane, but when dissolved in more polar solvents readily converts to 1. (C) 2008 Elsevier B. V. All rights reserved.