[ZnCl2(2,2'-oxydianiline)]2 | 1228461-96-8

• 英文名称: [ZnCl2(2,2'-oxydianiline)]2
• CAS: 1228461-96-8
• 化学式: C₂₄H₂₄Cl₄N₄O₂Zn₂
• 分子量: 673.072
• InChiKey: MHVMSASIZXQVKT-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-氨基苯基醚 、 zinc(II) chloride 以 异丙醇 为溶剂， 生成 [ZnCl2(2,2'-oxydianiline)]2
  参考文献：
  名称：

  Tetrahedral complexes of zinc(II) chloride with N- and O-containing organic ligands: Synthesis and crystal structures of [ZnCl2(C12H12N2O)] and [ZnCl2(H2O)2](Me4Pyz)2

  摘要：

  New complex chlorides [ZnCl2(ODA)] (I) (ODA=oxydianiline, C12H12N2O) and [ZnCl2(H2O)(2)](Me(4)Pyz)(2) (II) (Me(4)Pyz = 2,3,5,6-tetramethylpyrazine) were synthesized and crystallographically characterized. Crystals of I are monoclinic, space group C2/c, a = 22.682(2) , b = 12.646(1) , c = 9.951(1) , beta = 93.23(2)A degrees, V = 2849.7(5) (3), rho(calc) = 1.569 g/cm(3), Z = 8. Structure I contains cyclic fragments consisting of two tetrahedral complexes (ZnCl2N2) and two coordinated bridging oxydianiline ligands. Crystals of II are monoclinic, space group P2(1)/c, a = 8.972(2) , b = 13.862(3) , c = 17.528(4) , beta = 101.72(3)A degrees, V = 2134.5(7) (3), rho(calc) = 1.384 g/cm(3), Z = 4. In structure II, supramolecular pseudo-metallocycles are formed due to formation of hydrogen bonds O(w)-HaEuro broken vertical bar N between coordinated water molecules and noncoordinated nitrogen atoms of tetramethylpyrazine molecules.

  DOI：

  10.1134/s0036023609100167