RuCl3(2,6-di(imidazol-2-yl)pyridine) | 1241431-26-4

• 英文名称: RuCl3(2,6-di(imidazol-2-yl)pyridine)
• 英文别名: [Ru(H2L2)Cl3]
• CAS: 1241431-26-4
• 化学式: C₁₁H₉Cl₃N₅Ru
• 分子量: 418.655
• InChiKey: TVRQCCTVNGXKHB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  RuCl3(2,6-di(imidazol-2-yl)pyridine) 、 potassium [13C]cyanide 在 Zn 作用下， 以 氢氧化钾 为溶剂， 生成 K[Ru([(13)C]cyanide)3(2,6-di(imidazol-2-yl)pyridine)]
  参考文献：
  名称：

  Acceleration of Nucleophilic CH Activation by Strongly Basic Solvents

  摘要：

  (IPI)Ru(II)(OH)(n)(H2O)(m), where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to catalyze H/D exchange between hydrocarbons and strongly basic solvents at higher rates than in the case of the solvent alone. Significantly, catalysis by 2 is accelerated rather than inhibited by increasing solvent basicity. The evidence is consistent with the reaction proceeding by base modulated nucleophilic CH activation.

  DOI：

  10.1021/ja102518m
• 作为产物：
  描述：

  ruthenium(III)(H2O)3 chloride 、 2,6-双-(1H-咪唑-2-基)-吡啶 以 甲醇 为溶剂， 生成 RuCl3(2,6-di(imidazol-2-yl)pyridine)
  参考文献：
  名称：

  Acceleration of Nucleophilic CH Activation by Strongly Basic Solvents

  摘要：

  (IPI)Ru(II)(OH)(n)(H2O)(m), where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to catalyze H/D exchange between hydrocarbons and strongly basic solvents at higher rates than in the case of the solvent alone. Significantly, catalysis by 2 is accelerated rather than inhibited by increasing solvent basicity. The evidence is consistent with the reaction proceeding by base modulated nucleophilic CH activation.

  DOI：

  10.1021/ja102518m

文献信息

• 近红外发光钌配合物的制备及应用
  申请人：北京师范大学

  公开号：CN110511249B

  公开（公告）日：2020-10-30

  本发明公布了一个水溶性好的双核钌配合物的制备方法及其pH响应的近红外发光和单线态氧产生性质。