cis-Re(CO)4(P(i)Pr3)Cl | 219863-77-1

• 英文名称: cis-Re(CO)4(P(i)Pr3)Cl
• CAS: 219863-77-1
• 化学式: C₁₃H₂₁ClO₄PRe
• 分子量: 493.941
• InChiKey: JPOTUGJCCIQRTP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-Re(CO)4(P(i)Pr3)Cl 、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 二氯甲烷 为溶剂， 生成 [cis-(Re(CO)4(P(i)Pr3))2(μ-Cl)][B(3,5-(CF3)2C6H3)4]
  参考文献：
  名称：

  Rhenium Complexes with Weakly Coordinating Solvent Ligands, cis-[Re(PR₃)(CO)₄(L)][BAr_F], L = CH₂Cl₂, Et₂O, NC₅F₅:  Decomposition to Chloride-Bridged Dimers in CH₂Cl₂ Solution

  摘要：

  The solvent-coordinated complexes [cis-Re(CO)(4)(PR3)(S)][BArF] (R = Ph, Pr-i, Cy BArF = [B(3,5-(CF3)(2)C6H3)(4)](-)) for S = Et2O. CH(2)Chl(2) and NC5F5 have been prepared from reaction of the neutral methyl precursors, cis-Re-(CO)(4)(PR3)(Me), with either [H(OEt2)(2)][BArF] or [Ph3C][BArF] in the appropriate solvent. A crystal structure of the complex [cis-Re(CO)(4)((PPr3)-Pr-i)(ClCH2Cl)][BArF] shows that the dichloromethane ligand is coordinated through one chlorine, with an Re-Cl distance of 2.554(2) Angstrom. The first example of a structurally characterized pentafluoropyridine complex of rhenium was also determined, [cis-Re(CO)(4)((PPr3)-Pr-i)(NC5F5)][BArF], with an Re-N distance of 2.319(5) Angstrom. Activation of C-CI bonds in the dichloromethane complexes result in the formation of the chloride-bridged dimers, {[Cis-Re(CO)(4)(PR3)](2)(mu-Cl)}{BArF}, and the X-ray structures of the Ph and Cy derivatives were determined.

  DOI：

  10.1021/ic980912q
• 作为产物：
  描述：

  Rhenium, tetracarbonyl[tris(1-methylethyl)phosphine]- 在 四氯化碳 作用下， 以 正己烷 为溶剂， 生成 cis-Re(CO)4(P(i)Pr3)Cl
  参考文献：
  名称：

  Hanckel, John M.; Lee, Kang-Wook; Rushman, Paul, Inorganic Chemistry, 1986, vol. 25, # 11, p. 1852 - 1856

  摘要：

  DOI：