Synthesis of a Triosmium Carbonyl Cluster Complex with a Side-On-Coordinated Imine Ligand
作者:Jochem U. Köhler、Jack Lewis、Paul R. Raithby、Moira A. Rennie
DOI:10.1021/om961014+
日期:1997.8.1
A triosmiumcluster with a novel side-on coordinated imine ligand has been synthesized by the reaction between a triosmiumcarbenecomplex and ammonia. In the first step of the reaction, an anionic amino complex is formed which reacts upon treatment with [Ph3C]+ to abstract a hydride from the amino group to form the imine complex, the molecular structure of which has been determined.
Reactions of a Triosmium Cluster Complex with a Side-On-Coordinated Carbene Ligand with Sulfur Compounds Resulting in the Formation of a Thioketone Complex