Os3(CO)10(μ-η2-OCOSnPh3)(μ-OMe) | 1318805-07-0

• 英文名称: Os3(CO)10(μ-η2-OCOSnPh3)(μ-OMe)
• CAS: 1318805-07-0
• 化学式: C₃₀H₁₈O₁₃Os₃Sn
• 分子量: 1275.78
• InChiKey: SMRFUIXGLDCRMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲醇 、 Os3(CO)10(μ-η2-OCOSnPh3)(μ-OMe) 、 水 在 CF₃SO₃H 作用下， 以 甲醇 为溶剂， 以24%的产率得到Os3(CO)10(μ-OMe)(μ-OH)
  参考文献：
  名称：

  Complexes containing bridging tin- and germanium-substituted metallocarboxylate ligands from the reactions of Ph3SnOH and Ph3GeOH with Os3(CO)12 in the presence of base

  摘要：

  The first examples of bridging tin- and germanium-substituted metallocarboxylate ligands have been obtained from the reactions of Ph3SnOH and Ph3GeOH with Os-3(CO)(12) under basic conditions. Two products: Os-3(CO)(10)(mu-eta(2)-O=COSnPh3)(mu-OMe), 1 (18% yield) and Os-3(CO)(10)(mu-OMe)(mu-OH), 2 (6.9% yield) were obtained from the reaction of Ph3SnOH with Os-3(CO)(12) in the presence of [Bu4N]OH in methanol solvent. The compound Os-3(CO)(10)(mu-eta(2)-O=COGePh3)(mu-OMe), 3 (7.3% yield) was prepared similarly by using Ph3GeOH in place of Ph3SnOH. Each of the products 1-3 were characterized structurally by single-crystal X-ray diffraction analysis. Compounds 1 and 3 each contain an mu-eta(2)-O=COMPh3, M = Sn or Ge ligand bridging a pair of osmium atoms in a triosmium carbonyl cluster complex. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.03.008
• 作为产物：
  描述：

  甲醇 、 十二羰基三锇 、 三苯基氢氧化锡 以 甲醇 为溶剂， 以18%的产率得到Os3(CO)10(μ-η2-OCOSnPh3)(μ-OMe)
  参考文献：
  名称：

  Complexes containing bridging tin- and germanium-substituted metallocarboxylate ligands from the reactions of Ph3SnOH and Ph3GeOH with Os3(CO)12 in the presence of base

  摘要：

  The first examples of bridging tin- and germanium-substituted metallocarboxylate ligands have been obtained from the reactions of Ph3SnOH and Ph3GeOH with Os-3(CO)(12) under basic conditions. Two products: Os-3(CO)(10)(mu-eta(2)-O=COSnPh3)(mu-OMe), 1 (18% yield) and Os-3(CO)(10)(mu-OMe)(mu-OH), 2 (6.9% yield) were obtained from the reaction of Ph3SnOH with Os-3(CO)(12) in the presence of [Bu4N]OH in methanol solvent. The compound Os-3(CO)(10)(mu-eta(2)-O=COGePh3)(mu-OMe), 3 (7.3% yield) was prepared similarly by using Ph3GeOH in place of Ph3SnOH. Each of the products 1-3 were characterized structurally by single-crystal X-ray diffraction analysis. Compounds 1 and 3 each contain an mu-eta(2)-O=COMPh3, M = Sn or Ge ligand bridging a pair of osmium atoms in a triosmium carbonyl cluster complex. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.03.008