[Hg(PtCl(2,9-dimethyl-1,10-phenanthroline)(Z-MeO2CCH=CHCO2Me))2] | 153762-33-5

• 英文名称: [Hg(PtCl(2,9-dimethyl-1,10-phenanthroline)(Z-MeO2CCH=CHCO2Me))2]
• 英文别名: (Pt(2,9-dimethyl-1,10-phenanthroline)((Z)-MeO2CCHCHCO2Me)Cl)2Hg
• CAS: 153762-33-5
• 化学式: C₄₀H₄₀Cl₂HgN₄O₈Pt₂
• 分子量: 1366.44
• InChiKey: NUKMKKZEFJNKCN-AIYXTFOHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Hg(PtCl(2,9-dimethyl-1,10-phenanthroline)(Z-MeO2CCH=CHCO2Me))2] 、 silver tetrafluoroborate 在 H₂O 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 以70%的产率得到{(Pt(2,9-dimethyl-1,10-phenanthroline)((Z)-MeO₂CCHCHCO₂Me)H₂O)2Hg}{BF₄}2
  参考文献：
  名称：

  Trigonal-bipyramidal co-ordinatively saturated platinum(II) olefin complexes bearing an organomercury fragment in axial position

  摘要：

  The reactions of organomercury halides HgR'(Cl) (R' = Me, Et, Bu(t) or Ph) with complexes of the type [Pt(dmphen){(Z)-RO2CCH = CHCO2R}] (dmphen = 2,9-dimethyl-1,10-phenanthroline; R = Me, Et or Bu(t)) have been studied. The dmphen ligand with suitable 'in-plane' steric hindrance stabilizes five-co-ordinate adducts of general formula [PtCl(HgR')(dmphen){(Z)-ROCCH-CHCO2R}] when R' = alkyl. An influence of the nature of the Hg-bound hydrocarbyl group on the reaction course is observed. Thus, a cluster containing the Pt-Hg-Pt sequence was obtained when R' = Ph or Cl. The molecular structure of [PtCl(HgMe)(dmphen){(Z)-MeO2CCH=CHCO2Me}] (space group P2(1)/c; a = 13.079(2), b =1 3.167(2), c = 15.495(3) angstrom and beta = 94.18(2)-degrees] reveals a large trans influence of the organomercury fragment.

  DOI：

  10.1039/dt9930003421
• 作为产物：
  描述：

  {(Pt(2,9-dimethyl-1,10-phenanthroline)((Z)-MeO₂CCHCHCO₂Me)H₂O)2Hg}{BF₄}2 在 LiCl 作用下， 生成 [Hg(PtCl(2,9-dimethyl-1,10-phenanthroline)(Z-MeO2CCH=CHCO2Me))2]
  参考文献：
  名称：

  Trigonal-bipyramidal co-ordinatively saturated platinum(II) olefin complexes bearing an organomercury fragment in axial position

  摘要：

  The reactions of organomercury halides HgR'(Cl) (R' = Me, Et, Bu(t) or Ph) with complexes of the type [Pt(dmphen){(Z)-RO2CCH = CHCO2R}] (dmphen = 2,9-dimethyl-1,10-phenanthroline; R = Me, Et or Bu(t)) have been studied. The dmphen ligand with suitable 'in-plane' steric hindrance stabilizes five-co-ordinate adducts of general formula [PtCl(HgR')(dmphen){(Z)-ROCCH-CHCO2R}] when R' = alkyl. An influence of the nature of the Hg-bound hydrocarbyl group on the reaction course is observed. Thus, a cluster containing the Pt-Hg-Pt sequence was obtained when R' = Ph or Cl. The molecular structure of [PtCl(HgMe)(dmphen){(Z)-MeO2CCH=CHCO2Me}] (space group P2(1)/c; a = 13.079(2), b =1 3.167(2), c = 15.495(3) angstrom and beta = 94.18(2)-degrees] reveals a large trans influence of the organomercury fragment.

  DOI：

  10.1039/dt9930003421

文献信息

• Bi- and trinuclear cationic complexes involving bonds between mercury and five-coordinate platinum(II). Molecular structure of [{Pt(2,9-dimethyl-1,10-phenanthroline)-(Z-MeO2CCH = CHCO2Me)(H2O)}2 Hg](BF4)2
  作者：Maria E. Cucciolito、Federico Giordano、Francesco Ruffo、Vincenzo de Felice

  DOI：10.1016/0022-328x(95)05554-3

  日期：1995.11

  Three cationic five-coordinate platinum(II) complexes bearing alkylmercury fragments as ''ligands'' have been isolated. The complexes of general formula [Pt(HgR)H2O)dmphen)(ZR' O2CCH=CHCO(2)R')] (BF4) (dmphen=2,9-dimethyl-1,10-phenanthroline; R, R(t)=Me; R=Me, R(t) =(t)Bu; R=(t)Bu, R(t)=Me) are stabilized by the factors operating in related neutral species. Two of the new complexes slowly demercuriatez in solution, affording the mononuclear complexes [Pt(Me)H2O)(dmphen(ZR' O2CCH=CHCO(2)R(t))](BF4) (R(t)=Me or (t)Bu). When R=(t)Bu, a slow redistribution reaction is observed, yielding the trinuclear cluster [Pt(dmphen)(Z-MeO(2)CCH=CHCO(2)Me)H2O)}Hg-2](BF4)(2). The structure of this complex has been determined by X-ray analysis.