Re2(μ-N,N'-diphenylformamidinate)2Cl4 | 221247-28-5

• 英文名称: Re2(μ-N,N'-diphenylformamidinate)2Cl4
• 英文别名: trans-Re2Cl4(diphenylformamidinate)2
• CAS: 221247-28-5
• 化学式: C₂₆H₂₂Cl₄N₄Re₂
• 分子量: 904.713
• InChiKey: DINGFBOQQWSRDO-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• sp3杂化的碳原子比例：
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反应信息

• 作为产物：
  描述：

  Re2(diphenylformamidinate)3Cl3 在 HBF₄*Et₂O 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 生成 Re2(μ-N,N'-diphenylformamidinate)2Cl4
  参考文献：
  名称：

  Two diphenylformamidinate compounds of the quadruply-bonded Re26+ core

  摘要：

  The compounds Re-2(DPhF)(3)Cl-3 and Re-2(DPhF)(2)Cl-4 have been prepared and structurally characterized (DPhF =anion of N,N-diphenylformamidine). The former has three bridging DPhF ligands, two equatorial Cl ligands and one axial Cl ligand. The Re-Re distances in two different crystallographic forms are 2.2318(8) Angstrom and 2.2288(9) Angstrom. The second compound has two trans DPhF ligands and the Re2Cl4 unit is planar with Re-Re = 2.177(1) Angstrom, Re-Cl(av) = 2.319(5) Angstrom, Re-N(av)= 2.06(1) Angstrom and Cl-Re-Cl(av)= 106.0(1)degrees. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00325-9

文献信息

• Further studies on formamidinate dirhenium(III) complexes of the type Re2(μ-form)2Cl4 and the isolation and characterization of the ferrocenyl ligand Fe[η5-C5H4C(NHCy)(NCy)]2
  作者：N Dastagiri Reddy、Phillip E Fanwick、Richard A Walton

  DOI：10.1016/s0020-1693(01)00454-6

  日期：2001.7