(η5-cyclopentadienyl)(η4-1,2,5,6-cyclooctatetraene)rhodium | 55480-71-2

• 英文名称: (η5-cyclopentadienyl)(η4-1,2,5,6-cyclooctatetraene)rhodium
• CAS: 55480-71-2
• 化学式: C₁₃H₁₃Rh
• 分子量: 272.152
• InChiKey: OASIOJLWECVYFF-OHCXQOQLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η5-cyclopentadienyl)(η4-1,2,5,6-cyclooctatetraene)rhodium 生成 (η2,η3:η'2,η'3-C16H16)(η5-cyclopentadienyl)2dirhodium bis(hexafluorophosphate)
  参考文献：
  名称：

  Brammer, Lee; Connelly, Neil G.; Edwin, Joseph, Organometallics, 1988, vol. 7, # 6, p. 1259 - 1265

  摘要：

  DOI：
• 作为产物：
  描述：

  环戊二烯铊 、 {rhodium(μ-Cl)(η4-cyclooctatetraen)}2 以 甲苯 为溶剂， 以77%的产率得到(η5-cyclopentadienyl)(η4-1,2,5,6-cyclooctatetraene)rhodium
  参考文献：
  名称：

  Brammer, Lee; Connelly, Neil G.; Edwin, Joseph, Organometallics, 1988, vol. 7, # 6, p. 1259 - 1265

  摘要：

  DOI：

文献信息

• Synthetic and structural studies on (η5:η5-fulvalene)bimetallic compounds derived from (η5:η5-fulvalene)dithallium
  作者：Marvin D. Rausch、W.Craig Spink、Brian G. Conway、Robin D. Rogers、Jerry L. Atwood

  DOI：10.1016/0022-328x(90)85134-k

  日期：1990.2

  m (1) in 85–100% yield. Reactions of 1 with carbonyl halides of cobalt, rhodium, iridium, manganese and rhenium produce corresponding homobimetallic fulvalene metal carbonyls (2, 5, 9–11) in yields of 52–94%. The rhodium complex (η5 : η5-C10H8)Rh2(CO)4 (5) reacted with trimethylamine-N-oxide dihydrate to form a tricarbonyl derivative (η5 : η5-C10H8)Rh2(μ-CO)(CO)2 (6) that contained a bridging carbonyl

  dihydrofulvalene的无卤化物溶液和乙醇铊之间的反应产生了（η 5：η 5 -fulvalene）dithallium（1在85-100％产率）。的反应1与钴，铑，铱，锰，铼产生对应homobimetallic富瓦烯金属羰基化合物（羰基卤化物2，5，9 - 11）中的52-94％的产率。铑络合物（η 5：η 5 -C 10 ħ 8）的Rh 2（CO）4（5）与三甲胺反应Ñ氧化物二水合物，以形成三羰基衍生物（η 5：η 5 -C 10 ħ 8）的Rh 2（μ-CO）（CO）2（6包含一个桥接羰基和铑-铑键）。通过6与N-甲基-N-亚硝基脲的反应，桥连的羰基取代基可以被桥连的亚甲基取代。四（η 2 -亚乙基） - ，双（η 4 -1,2,5,6-环辛二烯） - ，双（η 4 -1,2,5,6-环辛四烯）（η 5：η 5 -fulvalene ）铑（12 – 14）已通过1与相应的氯
• The reactivity of complexed carbocycles
  作者：A. Salzer、T. Egolf、W. Von Philipsborn

  DOI：10.1016/s0022-328x(00)88377-1

  日期：1981.12

  a metal—metal bond with bridging fluxional cyclooctatetraene and fluxional olefinic ligands. The palladium complexes have a static pseudo-triple-decker structure with tub-shaped cyclooctatetraene coordinating with two double bonds each to two different organometallic moieties. All the complexes were characterized by 13C NMR spectroscopy. In the case of the fluxional molecules at low temperature the

  富电子的环辛酸酯复合物C 8 H 8 Fe（CO）3（I），C 5 H 5 CoC 8 H 8（II）和C 5 H 5 RhC 8 H 8（III）已经用铑，铱和钯的各种不饱和阳离子有机金属化合物处理，以高收率形成双金属产物。铑和铱配合物的共同结构特征是具有桥连的通量环辛酸酯和通量烯烃配体的金属-金属键。钯配合物具有静态的拟三联体结构，其桶形的环辛酸异戊烯与两个双键配位，每个双键与两个不同的有机金属部分配合。所有配合物均通过13 C NMR光谱表征。在流动性分子处于低温的情况下，末端烯烃配体的旋转运动足够慢，以便在慢交换极限下观察光谱。
• Bieri, Jost H.; Egolf, Thomas; Von Philipsborn, Wolfgang, Organometallics, 1986, vol. 5, # 12, p. 2413 - 2425
  作者：Bieri, Jost H.、Egolf, Thomas、Von Philipsborn, Wolfgang、Piantini, Umberto、Prewo, Roland、Ruppli, Urs、Salzer, Albrecht

  DOI：——

  日期：——
• Addition of cyclopropenylium and tropylium ions to cyclooctatetraene-cobalt and -rhodium cyclopentadienyl complexes
  作者：Neil G. Connelly、Philippa M. Hopkins、A. Guy Orpen、Jeremy Slater

  DOI：10.1039/dt9920003303

  日期：——

  Cyclopropenylium ions [C3R'3]+ (R' = Ph or Bu(t)) react with [Co(eta4-cot) (eta-C5R5)] (R = H or Me, cot = cyclooctatetraene) to give [Meta5-C8H8(C3R'3)}(eta-C5R5)]+ 3 (M = Co; R = H, R' = Ph; R = Me, R' = Ph or Bu(t)); X-ray structural studies on 3 (M = Co, R = H, R' = Ph) show an exo-cyclopropene substituent on the cyclooctatrienyl ring. The reaction of [C3Ph3]+ with [Rh(eta4-Cot)(eta-C5Me5)] gives a similar product 3 (M = Rh, R = Me, R' = Ph) which rearranges to an unknown isomer 5 whereas [Rh(eta4-cot)(eta-C5H5)] undergoes electrophilic substitution at the cyclopentadienyl ring to give [Rh (eta2, eta3-C8H9)eta-C5H4(C3Ph3)}]+ 4. The addition of [C7H7]+ to [Co(eta4-cot)(eta-C5R5)] (R = H or Me) gives [Coeta5-C8H8(C7H7)}(eta-C5R5)]+ 6 (R = H or Me) which, in the case of 6 (R = Me), rearranges to the 1,2,3,3a-tetrahydropentalenyl complex [Coeta5-C8H8(C7H7)}(eta-C5Me5)]+ 7. Finally, the reactions between [Rh(eta4-cot)(eta-C5R5)] (R = H or Me) and [C7H7]+ give [Rh(eta2, eta3-C8H9)eta-C5H4(C7H7)}]+ and [Rheta2, eta3-C8H8(C7H7)}(eta-C5Me5)]+ 9 respectively.
• Rearrangement mechanisms in slipped triple-decker complexes of cobalt and rhodium
  作者：Joseph Edwin、William E. Geiger、C. Hackett Bushweller

  DOI：10.1021/om00097a006

  日期：1988.7