[N(C4H9)4][Au(acetylacetonate)Cl] | 162857-34-3

• 英文名称: [N(C4H9)4][Au(acetylacetonate)Cl]
• CAS: 162857-34-3
• 化学式: C₅H₇AuClO₂*C₁₆H₃₆N
• 分子量: 573.997
• InChiKey: XXMMIPZBMNLTCB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [N(C4H9)4][Au(acetylacetonate)Cl] 、 以 二氯甲烷 为溶剂， 生成 三苯基膦氯金 、 (acetylacetonate)2Au2[CHP(C6H5)2AuP(C6H5)2]2
  参考文献：
  名称：

  Fernandez, Eduardo J.; Gimeno, M. Concepcion; Jones, Peter G., Chemische Berichte, 1995, vol. 128, # 2, p. 121 - 124

  摘要：

  DOI：

文献信息

• Synthesis, Structure, and Reactivity of the Anionic Trinuclear Methanide NBu4[{Au(C6F5)3(PPh2CHPPh2)}2Au]
  作者：Eduardo J. Fernandez、M. Concepcion Gimeno、Peter G. Jones、Antonio Laguna、Mariano Laguna、Jose M. Lopez-de-Luzuriaga

  DOI：10.1021/om00006a041

  日期：1995.6

  The reaction of [Au(tht)(2)]CLO(4) or NBu(4)[Au(acac)(2)] with 2 equiv of [Au(C6F5)(3)PPh(2)CH(2)PPh(2)] affords the cationic [Au(C6F5)(3)PPh(2)CH(2)PPh(2)}Au-2]ClO4 (1) or anionic complex NBu(4)[Au(C6F5)(3)PPh(2)CHPPh(2)}Au-2] (2), respectively, in high yield, The methanide complex 2 can displace tetrahydrothiophene from [AuX(tht)] to give the pentanuclear NBu(4)[AU(C6F6)(3)PPh(2)CH(AuX)PPh(2)}Au-2] (X = Cl, C6F5). The heptanuclear [Au(C6F5)(3)PPh(2)C(AuPPh(3))(2)PPh(2)}Au-2]ClO4 is obtained by reaction of 1 with [Au(acac)PPh(3)] (molar ratio 1:4), The structure of 2 has been determined by a single-crystal X-ray diffraction study, It crystallizes in the space group P (1) over bar with a = 14.213(4) Angstrom, b = 16.067(4) Angstrom, c = 23.840(6) Angstrom, alpha = 88.60(2)degrees, beta = 89.27(2)degrees, gamma = 71.23(2)degrees, Z = 2, and T = -100 degrees C, It does not display gold-gold interactions.