(η2-C60)Pt(PPh3)2 | 135863-99-9

• 英文名称: (η2-C60)Pt(PPh3)2
• 英文别名: η(2)-C60Pt(PPh3)2；(η2-C60)Pt(triphenylphosphine)2；(PPh3)2Pt(η2-C60)；bis(triphenylphosphine)platinum(η2-C60)
• CAS: 135863-99-9
• 化学式: C₉₆H₃₀P₂Pt
• 分子量: 1440.32
• InChiKey: BRZINUBQQFBTAQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane 、 (η2-C60)Pt(PPh3)2 以 甲苯 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  Chiral derivatives ofexo-metallofulierenes: Synthesis and X-ray study of solvate of platinumfullerene cluster with cyclooctene, ?2-C60Pt[(+)-D1OP] � C8H14

  摘要：

  A novel optically active exo-metallofullerene derivative, eta(2)-C60Pt[(+)-DIOP] (1) (DIOP is 2,3-o,o'-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphinobutane)), is formed as a result of the cleavage of the chelate metallocycle in Pt[(+)-DIOP](2) and the substitution of the bidentate (+)-DIOP ligand with C-60. Cluster 1 was also obtained by replacement of the phosphine ligands in eta(2)-C60Pt(PPh(3))(2) by (+)-DIOP. Compound 1 was identified by its electronic absorption spectra, P-31 NMR spectra, and the elemental analysis data. A single-crystal X-ray study of the 1 cyclooctene solvate, eta(2)-C-60,Pt[(+)-DIOP]. C8H14 was performed. Packing of the fullerene cores in a crystal of 1 . C8H14 corresponds to the diamond structure subjected to the significant orthorhombic distortions.

  DOI：

  10.1007/bf01431621
• 作为产物：
  描述：

  在 三苯基膦 作用下， 以 甲苯 为溶剂， 以75%的产率得到(η2-C60)Pt(PPh3)2
  参考文献：
  名称：

  Synthesis and Reactions of Organoplatinum Compounds of C₆₀, C₆₀Pt_n

  摘要：

  C60 的有机铂化合物 C60Ptn（n = 1-2）是通过 C60 与 Pt（dba）2 反应或 C60Ptn（n = 约 1）的热歧化反应制备的。获得的 C60Ptn 可催化二苯基乙炔的氢化反应，而与铂的含量无关。C60Ptn （n = 约 1）的碳-铂键的裂解是通过与膦或亚磷酸盐的反应完成的，这些反应提供了获得 (η2-C60)PtL2 [L = 磷化物和亚磷酸盐] 的一般途径。

  DOI：

  10.1246/cl.1994.1207

文献信息

• Electrochemical studies on metal derivatives of buckminsterfullerene (C60)
  作者：Susan A. Lerke、B. A. Parkinson、Dennis H. Evans、Paul J. Fagan

  DOI：10.1021/ja00046a029

  日期：1992.9

  The electrochemical properties of platinum, nickel, and palladium complex derivatives of buckministerfullerene are described.

  描述了降压型富勒烯的铂、镍和钯络合物衍生物的电化学性质。
• The reaction of diaryl derivatives of bis(triphenylphosphine)platinum(II) with [60]fullerene as a route to the platinum complex η2-C60Pt(PPh3)2
  作者：V. V. Bashilov、B. L. Tumanskii、P. V. Petrovskii、V. I. Sokolov

  DOI：10.1007/bf02496181

  日期：1999.3

  The reaction of cis-Ar2Pt(PPh3)(2) (Ar = p-MeC6H4 (1a) and Ar = Ph (fb)) with [60] fullerene in toluene afforded the metal-fullerene complex eta(2)-C60Pt(PPh3)(2) (2), which was isolated in the crystalline state. The reductive elimination between C-60 and la or Ib also resulted in the formation of biaryls (p-MeC6H4)(2) and Ph-Ph. The composition and structure of the compounds were established by H-1 and P-31 NMR spectroscopy, electronic absorption spectroscopy, and elemental analysis. The homolytic phosphorylation of 2 was additionally studied by the ESR method.