[Os(IV)(tris(pyrazol-1-yl)methane)Cl2(NPEt3)]PF6 | 371171-96-9

• 英文名称: [Os(IV)(tris(pyrazol-1-yl)methane)Cl2(NPEt3)]PF6
• CAS: 371171-96-9
• 化学式: C₁₆H₂₅Cl₂N₇OsP*F₆P
• 分子量: 752.465
• InChiKey: QGKUGRXVCNVUHL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Os(IV)(tris(pyrazol-1-yl)methane)Cl2(NPEt3)]PF6 在 ammonium cerium(IV) nitrate 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Preparation of Heteroatom Compounds by Stepwise Atom/Group Transfer in cis- and trans-[Os^VI(tpy)(Cl)₂(N)]⁺

  摘要：

  Rapid 2e(-) N- transfer reactions occur between both cis- and trans-[Os-VI(tpy)(Cl)(2)(N)](+) and Me2C6H3SH to give cis- and trans-[Os-IV(tpy)(Cl)(2)(NS(H)C6H3Me2)](+) with retention of stereo chemistry. These complexes undergo further reactions With PPh3 or p-MeOC6H4NH2 by net 2e(-), NSC6H3Me22- group transfer reactions to give the solvento complexes, cis- and trans- [Os-II(tpy)(Cl)(2)(NCCH3)], and the organic products, Ph3PNSC6H3Me2 and p-MeOC6H4N(H)NS(H)C6H3Me2, respectively. The sequential atom/group transfer reactions at the nitrido nitrogen atom provide a new stepwise synthetic route to PNS and NNS heteroatom compounds.[GRAPHICS]

  DOI：

  10.1021/ic010675i
• 作为产物：
  描述：

  (Os(VI)(tris(1-pyrazolyl)methane)(Cl)2(N))(1+) 、 三乙基膦 以 not given 为溶剂， 以95%的产率得到[Os(IV)(tris(pyrazol-1-yl)methane)Cl2(NPEt3)]PF6
  参考文献：
  名称：

  Preparation of Heteroatom Compounds by Stepwise Atom/Group Transfer in cis- and trans-[Os^VI(tpy)(Cl)₂(N)]⁺

  摘要：

  Rapid 2e(-) N- transfer reactions occur between both cis- and trans-[Os-VI(tpy)(Cl)(2)(N)](+) and Me2C6H3SH to give cis- and trans-[Os-IV(tpy)(Cl)(2)(NS(H)C6H3Me2)](+) with retention of stereo chemistry. These complexes undergo further reactions With PPh3 or p-MeOC6H4NH2 by net 2e(-), NSC6H3Me22- group transfer reactions to give the solvento complexes, cis- and trans- [Os-II(tpy)(Cl)(2)(NCCH3)], and the organic products, Ph3PNSC6H3Me2 and p-MeOC6H4N(H)NS(H)C6H3Me2, respectively. The sequential atom/group transfer reactions at the nitrido nitrogen atom provide a new stepwise synthetic route to PNS and NNS heteroatom compounds.[GRAPHICS]

  DOI：

  10.1021/ic010675i