ammonium (dipropylthiophosphate) | 35329-20-5

• 英文名称: ammonium (dipropylthiophosphate)
• 英文别名: thiophosphoric acid O,O'-dipropyl ester; ammonium salt
• CAS: 35329-20-5
• 化学式: C₆H₁₄O₃PS*H₄N
• 分子量: 215.254
• InChiKey: QWSUPESNXNOXGB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  二丁基氯化锗 、 ammonium (dipropylthiophosphate) 以 苯 为溶剂， 以98%的产率得到dibutylgermanium bis(dipropylthiophosphate)
  参考文献：
  名称：

  Garje, Shivram S.; Mokal, Vijaya B; Jain, Vimal K., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1995, vol. 34, # 10, p. 809 - 810

  摘要：

  DOI：

文献信息

• Diorganotin(IV) Dialkoxyphosphinothioates: Synthesis and Characterization
  作者：Vijaya B. Mokal、Vimal K. Jain

  DOI：10.1246/bcsj.68.1149

  日期：1995.4

  Diorganotin(IV) dialkoxyphosphinothioates of the general formula, [R2SnOSP(OR′)2}2] (R = Me, Et, Prn, Bun, But; R′ = Me, Prn or Bun), [R2Sn(Cl)OSP(OR′)2}] (R = Me or But; R′ = Prn or Bun), ([R2SnOSP(OR′)2}]2O)2 (R = Me, Prn; R′ = Prn) and [But2Sn(μ-OH)OSP(OR′)2}]2 (R′ = Me or Prn) have been synthesized. All of the complexes were characterized by elemental analyses as well as IR and multinuclear NMR (1H, 13C, 31P, and 119Sn) spectroscopy. The stereochemistry of these complexes is discussed based on the NMR data.

  通式为[R2SnOSP(OR′)2}2]（R＝Me、Et、Prn、Bun、But；R′＝Me、Prn 或 Bun）、[R2Sn(Cl)OSP(OR′)2}]（R＝Me 或 But；R′＝Prn或Bun）、（[R2SnOSP（OR′）2}]2O）2（R＝Me、Prn；R′＝Prn）和[But2Sn（μ-OH）OSP（OR′）2}]2（R′＝Me或Prn）的合成。所有复合物都通过元素分析、红外光谱和多核核磁共振（1H、13C、31P 和 119Sn）光谱进行了表征。根据核磁共振数据对这些复合物的立体化学进行了讨论。
• Monothiophosphorylation of Diorganotin Dichlorides. Synthesis and Characterization
  作者：Adnan A.S. El‐Khaldy

  DOI：10.1081/sim-120017778

  日期：2003.1.6

  Reactions of diorganotin dichlorides with ammonium dialkyl monothiophosphates in refluxing benzene in 1:2 molar ratio yield diorganotin bis(dialkyl monothiophosphate). These compounds are soluble in common organic solvents. Molecular weight determinations show that these compounds are associated in solution and the degree of association is concentration dependent. The new compounds have been characterized by elemental analyses as well as spectroscopic (IR, H-1, C-13, P-31 and Sn-119) studies. On the basis of these data, chelate structures have been proposed.
• Tyrkina,T.S. et al., Journal of general chemistry of the USSR, 1968, vol. 38, p. 167 - 169
  作者：Tyrkina,T.S. et al.

  DOI：——

  日期：——
• Itskova,A.L. et al., Journal of general chemistry of the USSR, 1971, vol. 41, # 12, p. 2651 - 2654
  作者：Itskova,A.L. et al.

  DOI：——

  日期：——
• Zimin, M. G.; Fomakhin, E. V.; Islamov, R. G., Journal of general chemistry of the USSR, 1985, vol. 55, # 12, p. 2384 - 2392
  作者：Zimin, M. G.、Fomakhin, E. V.、Islamov, R. G.、Pudovik, A. N.

  DOI：——

  日期：——