[Cu(2,9-dimethyl-1,10-phenanthroline)(triphenylphosphane)2]BF4 | 97567-29-8

• 英文名称: [Cu(2,9-dimethyl-1,10-phenanthroline)(triphenylphosphane)2]BF4
• 英文别名: 2,9-dimethyl-1,10-phenanthroline-bis(triphenyl)phosphine copper(I)tetrafluoroborate；[Cu(2,9-dimethyl-1,10-phenanthroline)(triphenylphosphane)₂]BF₄；[Cu(DMPhen)(PPh₃)₂]BF₄
• CAS: 97567-29-8
• 化学式: BF₄*C₅₀H₄₂CuN₂P₂
• 分子量: 883.195
• InChiKey: WJSNRPQZHDKABG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(2,9-dimethyl-1,10-phenanthroline)(triphenylphosphane)2]BF4 、 sulfur 以 二氯甲烷 为溶剂， 生成 2,9-dimethyl-1,10-phenanthrolinebis(triphenylphosphinesulfide)copper(I)
  参考文献：
  名称：

  Crystal structure and low-temperature emission of 2,9-dimethyl-1, 10-phenanthrolinebis(triphenylphosphinesulfide)copper(I)

  摘要：

  The synthesis and crystal structure of a luminescent Cu(l) complex containing triphenylphosphine sulfide and the alpha-diimine 2,9-dimethyl-1,10-phenanthroline (dmp) is described. The coordination geometry about the Cu(I) center is pseudo-tetrahedral. Interplanar interactions between phenyl groups on the phosphine sulfide ligands and the phenanthroline exist, but are significantly less than those previously reported for the Cu(I) triphenylphosphine analog. The complex displays emission from a single metal-centered charge-transfer state at 77K in a 4:1 ethanol/methanol (V/V) glass. This is in contrast to the triphenylphosphine complex, which exhibits dual luminescence from a charge-transfer and an intraligand state at 77K. Crystal data: orthorhombic, P2(1)2(1)2(1), a = 9.4226(9)Angstrom, b = 15.757(1)Angstrom, c = 30.494(6)Angstrom, V = 4527.4(6)Angstrom(3), and R = 0.053 (1021 reflections)

  DOI：

  10.1007/bf01668239
• 作为产物：
  描述：

  copper(II) tetrafluroborate hexahydrate 、 新铜试剂 在 PPh₃ 作用下， 以 乙醚 、 乙醇 为溶剂， 生成 [Cu(2,9-dimethyl-1,10-phenanthroline)(triphenylphosphane)2]BF4
  参考文献：
  名称：

  Photostudies of 2,2'-bipyridine bis(triphenylphosphine)copper(1+), 1,10-phenanthroline bis(triphenylphosphine)copper(1+), and 2,9-dimethyl-1,10-phenanthroline bis(triphenylphosphine)copper(1+) in solution and in rigid, low-temperature glasses. Simultaneous multiple emissions from intraligand and charge-transfer states

  摘要：

  DOI：

  10.1021/ja00409a048

文献信息

• Synthesis and study on a series of phosphorescent Cu(I) complexes having sterically blocking ligands
  作者：Kai Zhang、Dong Zhang

  DOI：10.1016/j.saa.2014.01.019

  日期：2014.4

  In this paper, we report six phosphorescent Cu(I) complexes with 1,10-phenanthroline-derived ligands and phosphorous ligands, including their synthesis, crystal structures, photophysical properties, and electronic nature. The Cu(I) center has a distorted tetrahedral geometry within the Cu(I) complexes. Theoretical calculation reveals that all emissions originate from triplet metal-to-ligand-charge-transfer

  在本文中，我们报告了六个具有1,10-菲咯啉衍生的配体和磷配体的磷光Cu（I）配合物，包括它们的合成，晶体结构，光物理性质和电子性质。Cu（I）中心在Cu（I）配合物中具有扭曲的四面体几何形状。理论计算表明，所有发射均源于三重态金属向配体电荷转移的激发态。发现将烷基部分引入1,10-菲咯啉的2,9-位对限制激发态中发生的几何弛豫非常有效，这大大增强了光致发光（PL）性能，包括PL量子产率的提高，PL衰变寿命增加，并且发射蓝移。
• Crystal structure and low-temperature emission of [(dmp)Cu(μ-S2butphos)2Cu(dmp)][BF4]2·6CH2Cl2 (dmp=2,9-dimethyl-1,10-phenanthroline; S2butphos=1,4-bis(diphenylphosphinesulfido)butane)
  作者：Randall K. Reigle、Dominick J. Casadonte、Simon G. Bott

  DOI：10.1007/bf01666965

  日期：1994.11

  The synthesis and crystal structure of a bimetallic luminescent Cu(I) complex containing 1,4-bis(diphenylphosphinesulfido)butane and the alpha-diimine 2,9-dimethyl-1,10-phenanthroline (dmp) is described. The coordination geometry about the Cu(I) center is pseudo-tetrahedral. Interplanar interactions between phenyl groups on the phosphine sulfide ligands and the phenanthroline exist which are indicative of intramolecular pi-stacking, leading to compressed S-Cu-S bond angles. The complex displays emission from a single metal-centered charge-transfer state at 77 K in a 4:1 ethanol/methanol (v/v) glass. This is in contrast to the triphenylphosphine complex, which exhibits dual luminescence from a charge-transfer and an intraligand state at 77 K. Crystal data: triclinic, P (1) over bar, a = 13.619(4)Angstrom, b = 13.673(2)Angstrom, c = 15.384(2)Angstrom, a = 75.08(1)degrees, beta 80.35(2)degrees, gamma = 80.67(2)degrees.