| 60955-41-1

• CAS: 60955-41-1
• 化学式: N₁₈P*Na
• 分子量: 306.084
• InChiKey: ZXXYBGPWHVFYDO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 bis(triphenylphosphoranylidene)ammonium azide 以 乙腈 为溶剂， 以76%的产率得到1,1,1-triphenyl-N-(triphenyl-l5-phosphaneylidene)-l5-phosphaniminium hexaazidophosphate(V)
  参考文献：
  名称：

  Experimental and Theoretical Characterization of the Hexaazidophosphate(V) Ion

  摘要：

  (PPN)[P(N(3))(6)] (2) was synthesized by the metathesis of Na[P(N(3))(6)] (1) and (PPN)N(3) (PPN(+) = {(Ph(3)P)(2)N}(+)), allowing for the isolation and full characterization of a stable hexaazidophosphate(V) salt by (31)P and (14)N NMR, UV absorption, IR and Raman spectroscopy, elemental and thermal analyses, X-ray diffraction, and Hartree-Fock and density functional theory calculations. The colorless single crystals of 2 are triclinic, space group P1, a = 9.6296(9), b = 9.8158(9), c = 10.1414(10) angstrom, alpha = 92.635(5)degrees, beta = 93.437(5)degrees, gamma = 92.105(4)degrees, and Z = 1. The [P(N(3))(6)](-) ion of 2 is isolated in the solid state and adopts S(6) symmetry both in the crystal and in solution. Thermogravimetric analysis and differential scanning calorimetry measurements reveal a surprising thermal stability of 2 (T(dec) ca. 200 degrees C). No friction sensitivity was encountered.

  DOI：

  10.1021/ic801536z
• 作为产物：
  描述：

  五氯化磷 、 sodium azide 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Experimental and Theoretical Characterization of the Hexaazidophosphate(V) Ion

  摘要：

  (PPN)[P(N(3))(6)] (2) was synthesized by the metathesis of Na[P(N(3))(6)] (1) and (PPN)N(3) (PPN(+) = {(Ph(3)P)(2)N}(+)), allowing for the isolation and full characterization of a stable hexaazidophosphate(V) salt by (31)P and (14)N NMR, UV absorption, IR and Raman spectroscopy, elemental and thermal analyses, X-ray diffraction, and Hartree-Fock and density functional theory calculations. The colorless single crystals of 2 are triclinic, space group P1, a = 9.6296(9), b = 9.8158(9), c = 10.1414(10) angstrom, alpha = 92.635(5)degrees, beta = 93.437(5)degrees, gamma = 92.105(4)degrees, and Z = 1. The [P(N(3))(6)](-) ion of 2 is isolated in the solid state and adopts S(6) symmetry both in the crystal and in solution. Thermogravimetric analysis and differential scanning calorimetry measurements reveal a surprising thermal stability of 2 (T(dec) ca. 200 degrees C). No friction sensitivity was encountered.

  DOI：

  10.1021/ic801536z

文献信息

• High-Energy-Density Materials: Synthesis and Characterization of N5+[P(N3)6]−, N5+ [B(N3)4]−, N5+ [HF2]−⋅n HF, N5+ [BF4]−, N5+ [PF6]−, and N5+ [SO3F]−
  作者：Ralf Haiges、Stefan Schneider、Thorsten Schroer、Karl O. Christe

  DOI：10.1002/anie.200454242

  日期：2004.9.20