[Ir2(CO)4(μ-SC(CH3)3)2] | 63312-27-6

• 英文名称: [Ir2(CO)4(μ-SC(CH3)3)2]
• CAS: 63312-27-6
• 化学式: C₁₂H₁₈Ir₂O₄S₂
• 分子量: 674.845
• InChiKey: WOCVVWNAAOOXCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ir2(CO)4(μ-SC(CH3)3)2] 以 正己烷 为溶剂， 生成 [Ir2(μ-SBu-t)2(CO)3(PMe3)]
  参考文献：
  名称：

  X-ray structures of two unexpected complexes isolated during carbonyl substitutions by phosphine ligands in dinuclear bridged d8 metal complexes

  摘要：

  DOI：

  10.1021/ja00375a021
• 作为产物：
  描述：

  以 乙腈 为溶剂， 以<100的产率得到[Ir2(CO)4(μ-SC(CH3)3)2]
  参考文献：
  名称：

  Electrochemistry of trimetallic ‘crown-like’ iridium(I) complexes

  摘要：

  DOI：

  10.1016/s0020-1693(00)83632-4

文献信息

• Guilmet, Elisabeth; Maisonnat, André; Poilblanc, René, Organometallics, 1983, vol. 2, # 9, p. 1123 - 1127
  作者：Guilmet, Elisabeth、Maisonnat, André、Poilblanc, René

  DOI：——

  日期：——
• Trinuclear "crown-like" metal complexes: an unusual product of reaction of activated alkynes with dinuclear thiolato-bridged iridium complexes
  作者：J. Devillers、J. J. Bonnet、D. De Montauzon、J. Galy、R. Poilblanc

  DOI：10.1021/ic50203a032

  日期：1980.1
• Low temperature matrix photochemistry of M2(CO)4(μ-S-t-Bu)2 and [M(CO)2Cl2]1− anions, where M=Rh and Ir
  作者：Thomas E. Bitterwolf、Byron Wong

  DOI：10.1016/j.ica.2004.06.034

  日期：2004.11

  Photolysis of M-2(CO)(4)(mu-S-t-Bu)(2), where M = Rh or Ir, in Nujol matrices at ca. 90 K results in simple CO loss to form a tricarbonyl intermediate analogous to that observed for Rh-2(CO)(4)(mu-Cl)(2). Photolysis of the anions, [M(CO)(2)Cl-2](1-), where M = Rh or Ir, in inert ionic matrices at ca. 90 K, results in CO-loss to form an intermediate analogous to that formed by Rh(CO)(2)(i-Pr2HN)Cl. Finally, photolysis of trans-Ir(CO)(PMe3)(2)Cl in a Nujol matrix at ca. 90 K gives rise to a new species whose carbonyl band is shifted slightly down in energy as has been observed for trans-Rh(CO)(PMe3)(2)Cl. In all cases the iridium compounds behave similarly to the rhodium species although the photon energy for iridium photochemistry is typically above that of the rhodium compounds. (C) 2004 Elsevier B.V. All rights reserved.
• Claver, Carmen; Fis, Joëlle; Kalck, Philippe, Inorganic Chemistry, 1987, vol. 26, # 21, p. 3479 - 3482
  作者：Claver, Carmen、Fis, Joëlle、Kalck, Philippe、Jaud, Joël

  DOI：——

  日期：——
• El Amane, Mohamed; Maisonnat, André; Dahan, Françoise, Organometallics, 1985, vol. 4, # 4, p. 773 - 780
  作者：El Amane, Mohamed、Maisonnat, André、Dahan, Françoise、Pince, Robert、Poilblanc, René

  DOI：——

  日期：——