{Mn2(CO)6(η-S2CP(C6H11)3)} | 112834-91-0

• 英文名称: {Mn2(CO)6(η-S2CP(C6H11)3)}
• 英文别名: Mn2(CO)6(μ-S2CPCy3)；[mn2(CO)6(μ-S2CPCy3)]
• CAS: 112834-91-0
• 化学式: C₂₅H₃₃Mn₂O₆PS₂
• 分子量: 634.515
• InChiKey: LJVONLYLYIOZDK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Mn2(CO)6(η-S2CP(C6H11)3)} 在 Br₂ 作用下， 以 not given 为溶剂， 以25-35的产率得到fac-Mn(CO)3Br(S2CP(cyclohexyl)3)
  参考文献：
  名称：

  Miguel, Daniel; Riera, Víctor; Miguel, Jesús A., Organometallics, 1991, vol. 10, # 6, p. 1683 - 1692

  摘要：

  DOI：
• 作为产物：
  描述：

  在 allyl bromide or (CH₃(CH₂)3)3SnCl 作用下， 以 not given 为溶剂， 生成 {Mn2(CO)6(η-S2CP(C6H11)3)}
  参考文献：
  名称：

  Alkylation and metalation of binuclear anions containing a novel tricyclohexylphosphonioethanetrithiolate ligand S(SR)CC(PCy3)S

  摘要：

  The reaction of homobinuclear rhenium-rhenium complex [Re-2(CO)(6)(mu-S2CPCy3)] (1c) with Li[BHEt3] in THF produces anionic 2c which reacts with CS2 affording a new anion 3c, through desulfurization and CS insertion, in a fashion paralel to that of the perviously known Mn-Mn and Mn-Re analogues. Anions 3a-3c undergo allylation and metallation to give neutral products 4a-4k. The structures of [MnRe(CO)(6)(mu-H){mu-S(SSnBu3")C=C(PCy3)S}] (4d) and [MnRe(CO)(6)(mu-H){mu-S(SC3H5)C=C(PCy3)S}] (4h) have been determined by X-ray diffraction revealing the (OC)(3)Mn-Re(CO)(3) core unit bridged by hydride and the novel S-tributylstannyl-, or (S-allyl)-(tricyclohexylphosphonio)ethenetrithiolate ligands. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.019

文献信息

• New bonding mode of tricyclohexylphosphoniodithiocarboxylate (S₂CPCy₃) as an eight-electron donor. Synthesis, reactivity, and X-ray crystal structure of [Mn₂(CO)₆(S₂CPCy₃)]
  作者：Daniel Miguel、Victor Riera、Jesús A. Miguel、Xavier Soláns、Manuel Font-Altaba

  DOI：10.1039/c39870000472

  日期：——

  Mn2(CO)10 with the tricyclohexylphosphine–carbon disulphide adduct S2CPCy3 in refluxing toluene affords the dinuclear complex [Mn2(CO)6(S2CPCy3)](1) in good yield, the structure of which, determined by X-ray crystallography, shows a new mode of co-ordination of the S2CPCy3 ligand which is bonded to an Mn atom by two sulphur atoms and to the other Mn atom by two sulphur and one carbon atom donating 8 electrons;

  Mn 2（CO）10与三环己基膦-二硫化碳加合物S 2 CPCy 3在回流的甲苯中反应得到双核配合物[Mn 2（CO）6（S 2 CPCy 3）]（1），产率高，结构其中，通过X射线晶体学测定，显示了S 2 CPCy 3配体的新配位模式，该配体通过两个硫原子键合到一个Mn原子上，并且通过两个硫原子和一个碳原子键合到另一个Mn原子上8个电子；（1）与中性单齿配体L的热反应产生[Mn2（CO） 5（S 2 CPCy 3）（L）]通过CO位移。
• Carbon−Sulfur Bond Cleavage of S₂CPR₃ Ligands in Dinuclear Complexes Promoted by Reduction and Protonation
  作者：Jing Li、Daniel Miguel、M. Dolores Morales、Víctor Riera、Santiago García-Granda

  DOI：10.1021/om971074v

  日期：1998.8.1

  Complexes [Mn-2(CO)(6)(mu-S2CPR3)] (R = Cy (1a), Pr-i (1b)) are reduced with Na[Hg] in THF to afford the anions [Mn-2(CO)(6)(mu-S2CPR3)](2-) (2a,b), which give neutral unstable [Mn-2(CO)(6)-(mu-SH) mu-SC(H)PR3}(NH3)] (3a,b) upon protonation with excess NH4PF6. The NH3 ligand of 3a,b is readily replaced by PEt3 to obtain [Mn-2(CO)(6)(mu-SH)mu-SC(H)PR3}(PEt3)] (5a,b) as stable crystalline solids, which have been isolated and characterized. The same reduction/ protonation sequence when applied to the dirhenium analogue [Re-2(CO)(6)(mu-S2CPCy3)] (1c) affords stable crystalline [Re-2(CO)(6)(mu-SH)mu-SC(H)PCy3}(NH3)] (6). An X-ray determination revealed that 6 contains one bridging SH- and the novel ligand Cy3PC(H)S- which is bonded as mu(2)-eta(1)(S); eta(2)(C,S'), donating 5e to the metals. Both bridging ligands are produced from the cleavage of one C-S bond of the starting S2CPR3 during the reduction/protonation process, which can be regarded globally as hydrogenolysis of the C-S bond. Additionally, the Re-Re bond is also cleaved during the process. As their dimanganese analogues, 6 undergo easy substitution of NH3 by PEt3 to give [Re-2(CO)(6)(mu-SH)mu-SC(H)PCy3}(PEt3)] (7). Comparison of the spectroscopic data indicate that both series of compounds are isostructural, with the only difference being the higher stability of the dirhenium complexes when compared to those of dimanganese.
• Alvarez, Bernardo; García-Granda, Santiago; Jeannin, Yves, Organometallics, 1991, vol. 10, # 9, p. 3005 - 3007
  作者：Alvarez, Bernardo、García-Granda, Santiago、Jeannin, Yves、Miguel, Daniel、Miguel, Jesús A.、Riera, Víctor

  DOI：——

  日期：——
• Alvarez, Bernardo; Miguel, Daniel; Riera, Victor, Organometallics, 1991, vol. 10, # 2, p. 384 - 387
  作者：Alvarez, Bernardo、Miguel, Daniel、Riera, Victor、Miguel, Jesús A.、García-Granda, Santiago

  DOI：——

  日期：——
• Alvarez, Bernardo; García-Granda, Santiago; Li, Jing, Organometallics, 1994, vol. 13, # 1, p. 16 - 17
  作者：Alvarez, Bernardo、García-Granda, Santiago、Li, Jing、Miguel, Daniel、Riera, Victor

  DOI：——

  日期：——