[NiCl2(N,N-bis(dicyclohexylphosphinomethyl)methylamine)] | 1161882-47-8

• 英文名称: [NiCl2(N,N-bis(dicyclohexylphosphinomethyl)methylamine)]
• CAS: 1161882-47-8
• 化学式: C₂₇H₅₁Cl₂NNiP₂
• 分子量: 581.252
• InChiKey: FKOBGOGAFDLGNY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  D-谷氨酸 、 [NiCl2(N,N-bis(dicyclohexylphosphinomethyl)methylamine)] 在 silver(l) oxide 作用下， 以 二氯甲烷 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Synthesis of Some Nickel(II) Diphosphine Complexes Having Coordinated Carboxylates

  摘要：

  Treatment of aminobis(methylphosphine) complexes of nickel(II) with carboxylic acids in the presence of silver(I) salts in dichloromethane gives the corresponding nickel(II) complexes of the type [NiA(P-P] where A = CO(3)(--) (carbonate), (2),2-(-) OC(6)H(4)CO(2)(-) (salicylate, Sal), (3),(-)O(2)CCH(2)CH(2) CH(NH(2))CO(2)(-) (glutamate, Glu), (4), (-)O(2) CCH(2)CH(2)CO(2)(-) (succinicate, Suc), (5); P-P = (Cy(2)PCH(2))(2)NMe (dcpam), (Ph(2)PCH(2))(2)NMe (dppam). The complexes have been characterized by spectroscopic techniques such as (31)P-{(1)H} NMR, FT-IR, UV-Vis. and mass spectrometry.

  DOI：

  10.1080/15533170802255351
• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 N,N-bis(dicyclohexylphosphinomethyl)methylamine 以 not given 为溶剂， 生成 [NiCl2(N,N-bis(dicyclohexylphosphinomethyl)methylamine)]
  参考文献：
  名称：

  Synthesis of Some Nickel(II) Diphosphine Complexes Having Coordinated Carboxylates

  摘要：

  Treatment of aminobis(methylphosphine) complexes of nickel(II) with carboxylic acids in the presence of silver(I) salts in dichloromethane gives the corresponding nickel(II) complexes of the type [NiA(P-P] where A = CO(3)(--) (carbonate), (2),2-(-) OC(6)H(4)CO(2)(-) (salicylate, Sal), (3),(-)O(2)CCH(2)CH(2) CH(NH(2))CO(2)(-) (glutamate, Glu), (4), (-)O(2) CCH(2)CH(2)CO(2)(-) (succinicate, Suc), (5); P-P = (Cy(2)PCH(2))(2)NMe (dcpam), (Ph(2)PCH(2))(2)NMe (dppam). The complexes have been characterized by spectroscopic techniques such as (31)P-{(1)H} NMR, FT-IR, UV-Vis. and mass spectrometry.

  DOI：

  10.1080/15533170802255351