Relative reactivities of anionic transition metal hydrides. Reduction of alkyl halides
作者:S. C. Kao、Marcetta Y. Darensbourg
DOI:10.1021/om00082a030
日期:1984.4
Phase-transfer photolysis of metal hexacarbonyls
作者:Horst Kunkely、Arnd Vogler
DOI:10.1021/om00046a008
日期:1992.10
The photochemical conversion of M(CO)6 (M = Cr, Mo, W) to M(CO)5X- (X = halogen) across a hexane/water interface leads to a separation of the reactant and product. This process may be of general importance for synthetic applications. Under suitable conditions inner-filter effects and secondary photolysis can be avoided.
Photochemical disproportionation reactions of the W 2 (CO) 10 2− and Fe 2 (CO) 8 2− complexes