| 878282-08-7

• CAS: 878282-08-7
• 化学式: C₃₂H₈₀N₁₂Zn₂
• 分子量: 763.848
• InChiKey: MFVNRJIJJBDGLH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  乙醇 、 以 甲苯 为溶剂， 以70%的产率得到(C₂H₅O)4Zn₃[N(CH₂CH₂N(CH₃)2)2]2
  参考文献：
  名称：

  Synthesis and structures of zinc alkoxo, aryloxo and hydroxo complexes with an amidodiamine ligand

  摘要：

  The synthesis and characterization of zinc complexes bearing an amidodiamine ligand, (EtO)(4)Zn(3)[N(CH(2)CH(2)NMe(2))(2)](2) (1), [Et(3)CO)ZnN(CH(2)CH(2)NMe(2))(2)](2) (2) and [(2,6-(i)Pr(2)C(6)H(3)O)ZnN(CH(2)CH(2) NMe(2))(2)](2) (3), [(Me(3)Si)(2)N]Zn[N(CH(2)CH(2)NMe(2))(2)] (4) and [(Me(3)Si)(2)N](2)Zn(2)(OH)[N(CH(2)CH(2)NMe(2))(2)] (5), are reported. Compounds 1-3 are synthesised in the reactions of {Zn[N(CH(2)CH(2)NMe(2))(2)](2)}(2) with 2 equiv. of ethanol, 3-ethyl-3-pentanol and 2,6-diisopropylphenol, respectively. Compound 4 is obtained by the reaction of Zn[N(SiMe(3))(2)](2) with HN(CH(2)CH(2)NMe(2))(2), and compound 5 is synthesised by reacting 4 with 1 equiv. of H(2)O. Compound 4 is characterized by NMR and MS while all of the other compounds are characterized with NMR, MS, elemental analysis and single-crystal X-ray diffraction. Compound 1 is a trinuclear species containing a Zn(3)N(2)O(2) core. Compounds 2 and 3 are dimeric with planar Zn(2)N(2) rings. Compound 5 is dimeric with a planar Zn(2)NO ring. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.06.029
• 作为产物：
  描述：

  N'-[2-(二甲基氨基)乙基]-N,N-二甲基乙二胺 、 bis(diisobutylamido)zinc 以 乙醚 为溶剂， 以52%的产率得到
  参考文献：
  名称：

  Syntheses and X-ray crystal structures of zinc complexes with an amido-diamine ligand

  摘要：

  The synthesis and characterization of complexes with a tridentate amido-diamine ligand N(CH2CH2NMe2)(2), [ClZnN(CH2CH2NMe2)(2)](2) (1), [EtZnN(CH(2)CH(2)NMel)(2)](2) (2), JZn[N(CH(2)CH2NMe(2))(2)](2)}(2) (3) and [(Bu2NZnN)-Bu-t(CH2CH2NMe2)(2)](2) (4), are described. Compounds 1 (57% yield) and 2 (49% yield) were obtained from the reactions of ZnCl2 with 1 equiv. of LiN(CH2CH2NMe2)(2) and ZnEt2 with excess HN(CH2CH2NMe2)(2), respectively. Compounds 3 (52% yield) and 4 (75% yield) were isolated from the reactions of [Zn((NBu2)-Bu-i)(2)](2) With HN(CH2CH2NMe2)(2) in 1:4 and 1:2 molar ratios, respectively. Mass spectral data and NMR analyses suggested that all four compounds were dimeric. The solid-state structures of compounds 2 and 3 were determined via X-ray crystallography. Both compounds were centrosymmetric containing a four-membered Zn2N2 ring with bridging amido ligands. In both structures, one NMe2 group in each bridging ligand bonded to a Zn center forming a five-membered ring. The ethyl groups in 2 and the second -N(CH2CH2NMe2)(2) ligand in 3 occupied the terminal positions. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.06.041