[Pt(CH3)(H2O)(2,9-dimethyl-1,10-phenanthroline)(dimethyl maleate)]BF4 BF4(1-)*C21H25N2O5Pt(1+), yellow | 180396-28-5

• 英文名称: [Pt(CH3)(H2O)(2,9-dimethyl-1,10-phenanthroline)(dimethyl maleate)]BF4 BF4(1-)*C21H25N2O5Pt(1+), yellow
• 英文别名: [Pt(2,9-dimethyl-1,10-phenanthroline)(dimethyl maleate)(H2O)Me]BF4；[PtMe(H2O)(2,9-Me2-1,10-phenanthroline)(dimethylmaleate)]BF4
• CAS: 180396-28-5
• 化学式: BF₄*C₂₁H₂₅N₂O₅Pt
• 分子量: 667.325
• InChiKey: SDUQAEXPOXVOPB-BQRHYOBJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(CH3)(H2O)(2,9-dimethyl-1,10-phenanthroline)(dimethyl maleate)]BF4 BF4(1-)*C21H25N2O5Pt(1+), yellow 、 N,N-dimethyldiazoacetamide 以 甲醇 为溶剂， 以35%的产率得到[PtMe(2,9-Me2-1,10-phenathroline)(η(1),η(2)-CH(CONMe2)O2CCH=CHCO2Me)]
  参考文献：
  名称：

  First Coordinatively Saturated Carbene Complexes of Platinum(II):  Synthesis, Structure, and Reactivity

  摘要：

  Coordinatively saturated carbene complexes of platinum(II) have been obtained by oxidative addition of [ClCH=NMe2]Cl to Pt(0) precursors. The cationic products of general formula [PtCl(CHNMe2)(N,N-chelate)(olefin)]Cl have been characterized through NMR spectroscopy and for [PtCl(CHNMe2)(2,9-Me-2-1,10-phen)(Z-MeO2CCH=CHCO2Me)]Cl by X-ray diffractometry. The latter species reacts with nucleophiles affording dimethylformamide and the corresponding Pt(0) precursor [Pt(2,9-Me-2-1,10-phen)(Z-MeO2CCH=CHCO2Me)]. Attempts to obtain related complexes containing carbene groups Pt=CHY without a heteroatom in alpha-position (Y = CO2Et, CO2NMe2, CN) have led to the isolation of complexes of formula [PtR(dmphen){eta(1),eta(2)-CH(Y)O2CCH=CHCO2Me}] (R = Me, Ph), Formally derived fi om an intrasnolecular nucleophilic addition to a carbene intermediate. The X-ray structure of a representative product, [PtMe(dmphen){eta(1),eta(2)-CH(CO2Et)O2CCH=CHCO2Me}], is reported.

  DOI：

  10.1021/om990240r

文献信息

• Organometallic polymers containing coordinatively saturated platinum(II) complexes as pendants
  作者：Barbara Panunzi、Antonio Roviello、Francesco Ruffo、Alfredo Vivo

  DOI：10.1016/s0020-1693(98)00157-1

  日期：1998.11

  The synthesis and some properties of soluble organometallic polymers which contain trigonal bipyramidal platinum(II) complexes as pendants are described. An N,N-chelate and an olefin define the equatorial plane of the complex, while two anionic ligands, or one anion and a pyridine nitrogen, occupy the axial positions. Each of the coordination sites was used to anchor the organometallic fragments to

  描述了包含三角形双锥体铂（II）配合物作为侧基的可溶性有机金属聚合物的合成和某些性能。N，N-螯合物和烯烃限定了络合物的赤道面，而两个阴离子配体或一个阴离子和吡啶氮占据了轴向位置。每个配位位点都用于将有机金属片段固定在聚合物链上。