[(ferrocenyl)(C6H2I(CH2NMe2)2)] | 914613-80-2

• 英文名称: [(ferrocenyl)(C6H2I(CH2NMe2)2)]
• CAS: 914613-80-2
• 化学式: C₂₂H₂₇FeIN₂
• 分子量: 502.221
• InChiKey: UUTNVXMUZFXNKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(ferrocenyl)(C6H2I(CH2NMe2)2)] 、 [Pt₂(4-MeC₆H₄)₄(μ-SEt₂)₂] 以 甲苯 为溶剂， 以71%的产率得到(η5-C5H5)(η5-C5H4C6H2(CH2NMe2)2-2,6-PtI)Fe
  参考文献：
  名称：

  Heterobimetallic Fe–Pd and Fe–Pt NCN pincer complexes (NCN=[C6H2(CH2NMe2)2-2,6]−)

  摘要：

  The meta-diaminoaryl ferrocenes Fc-NCN-H (3) and Fc-C C-NCN-H (5) (Fc = (eta(5)-C5H5)(eta(5)-C5H4)Fe, NCN-H = C6H3(CH2NMe2)(2)-3,5) can be used as precursors in the preparation of heterobimetallic transition metal complexes of structural type Fc-NCN-MX (NCN = [C6H2(CH2NMe2)(2)-2,6](-); MX = PdCl (7), PtCl (8), PtI (9)) and Fc-C C-NCN-MX (MX = PdCl (11), PdI (12), PtCl (13)), respectively. They are accessible by applying different synthesis procedures, including oxidative addition and metallation-transmetallation processes.Cyclovoltammetric studies show that the ferrocene moieties in 3, 5, 7-9 and 11-13 can reversibly be oxidised. The potential of the Fe(II)/Fe(III) redox couple decreases with increasing electron density at the NCN pincer unit. The use of 8 as a possible (electro)chemical sensor in the detection of SO, is discussed as well.The solid-state structures of 8 and 13 are reported. The crystals of 8 contain two molecules of 8 in the asymmetric unit. The plane of the C6H2 moiety is with 27.2(3)degrees and 38.2(3)degrees tilted towards the C5H4 entity, while in 13 an angle of 45.9(3)degrees can be found. The d(8)-electron configured platinum atoms possess a somewhat distorted square-planar surrounding, setup by two Me2NCH2 ortho-substituents, the NCN C-ipso carbon atom and the chloride ligand. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.05.045
• 作为产物：
  描述：

  (η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)] 、 碘 在 n-BuLi 作用下， 以 乙醚 为溶剂， 以82%的产率得到[(ferrocenyl)(C6H2I(CH2NMe2)2)]
  参考文献：
  名称：

  Heterobimetallic Fe–Pd and Fe–Pt NCN pincer complexes (NCN=[C6H2(CH2NMe2)2-2,6]−)

  摘要：

  The meta-diaminoaryl ferrocenes Fc-NCN-H (3) and Fc-C C-NCN-H (5) (Fc = (eta(5)-C5H5)(eta(5)-C5H4)Fe, NCN-H = C6H3(CH2NMe2)(2)-3,5) can be used as precursors in the preparation of heterobimetallic transition metal complexes of structural type Fc-NCN-MX (NCN = [C6H2(CH2NMe2)(2)-2,6](-); MX = PdCl (7), PtCl (8), PtI (9)) and Fc-C C-NCN-MX (MX = PdCl (11), PdI (12), PtCl (13)), respectively. They are accessible by applying different synthesis procedures, including oxidative addition and metallation-transmetallation processes.Cyclovoltammetric studies show that the ferrocene moieties in 3, 5, 7-9 and 11-13 can reversibly be oxidised. The potential of the Fe(II)/Fe(III) redox couple decreases with increasing electron density at the NCN pincer unit. The use of 8 as a possible (electro)chemical sensor in the detection of SO, is discussed as well.The solid-state structures of 8 and 13 are reported. The crystals of 8 contain two molecules of 8 in the asymmetric unit. The plane of the C6H2 moiety is with 27.2(3)degrees and 38.2(3)degrees tilted towards the C5H4 entity, while in 13 an angle of 45.9(3)degrees can be found. The d(8)-electron configured platinum atoms possess a somewhat distorted square-planar surrounding, setup by two Me2NCH2 ortho-substituents, the NCN C-ipso carbon atom and the chloride ligand. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.05.045

文献信息

• Organometallic π-Tweezers, NCN Pincers, and Ferrocenes as Molecular “Tinkertoys” in the Synthesis of Multiheterometallic Transition-Metal Complexes
  作者：Heinrich Lang、Rico Packheiser、Bernhard Walfort

  DOI：10.1021/om058042p

  日期：2006.4.1

  describes the synthesis, reaction chemistry, structures, and bonding of early−late heterodi-, heterotri-, and heterotetrametallic transition-metal complexes by applying the molecular “Tinkertoy” approach. As connecting units between the different metal atoms, π-conjugated carbon-rich organic and/or inorganic groups can be used. The electrochemical behavior of such one-dimensional molecular wire molecules

  这篇综述通过分子“ Tinkertoy”方法描述了早晚异二，异三和异四金属过渡金属配合物的合成，反应化学，结构和键合。作为不同金属原子之间的连接单元，可以使用π共轭的富含碳的有机和/或无机基团。还分别给出了这种一维分子线分子，配位聚合物，星形结构和树状取向过渡金属物种的电化学行为。