[(titanium)2(catecholate)4(dimethylacetamide)2] | 1442106-39-9

• 英文名称: [(titanium)2(catecholate)4(dimethylacetamide)2]
• 英文别名: Ti2(catecholate)4(dimethylacetamide)2；[Ti2(cat)4(DMA)2]
• CAS: 1442106-39-9
• 化学式: C₃₂H₃₄N₂O₁₀Ti₂
• 分子量: 702.389
• InChiKey: VNRFXWTYYJDSCQ-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  吡啶 、 [(titanium)2(catecholate)4(dimethylacetamide)2] 反应 48.0h， 以53%的产率得到[(titanium)10(O)12(catecholate)8(pyridine)8]*2(pyridine)
  参考文献：
  名称：

  An unprecedented high nuclearity catecholato-based Ti(iv)-architecture bearing labile pyridine ligands

  摘要：

  与可见光吸收特性相关的解决方案中，S4对称性[Ti10O12(cat)8(py)8]复合物的原始行为使得这种化合物成为生成基于钛的配位聚合物的良好候选者。

  DOI：

  10.1039/c3dt53424c
• 作为产物：
  描述：

  异丁酰胺 、 [Ti8O8(tert-butyl acetate)16] 、 邻苯二酚 以 乙醇 为溶剂， 以66%的产率得到[(titanium)2(catecholate)4(dimethylacetamide)2]
  参考文献：
  名称：

  Toward colored reticular titanium-based hybrid networks: Evaluation of the reactivity of the [Ti8O8(OOCCH2But)16] wheel with phenol, resorcinol and catechol

  摘要：

  The work presented here concerns the evaluation of the reactivity of the [Ti8O8(OOCCH2But)(16)] cluster towards phenol, resorcinol and catechol using NMR techniques. Whereas the reactions conducted in the presence of phenol and resorcinol showed to be particularly slow, it appeared that catechol allowed the quantitative displacement of the carboxylato ligands. Upon addition of a large excess of catechol, a complete transformation of the [Ti8O8] core was noticed leading to final products formulated as Ti-2(cat)(4)(L)(2) (L = DMA, DMF). (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.04.021